1-Octene
- Formula: C8H16
- Molecular weight: 112.2126
- IUPAC Standard InChIKey: KWKAKUADMBZCLK-UHFFFAOYSA-N
- CAS Registry Number: 111-66-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: α-Octene; α-Octylene; n-1-Octene; Caprylene; 1-C8H16; Oct-1-ene; Octene-1; Neodene 8; Octylene; 1-n-Octene; NSC 8457; SHOP C8
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Kovats' RI, non-polar column, isothermal
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Packed | Capillary | Capillary | Packed | Capillary |
---|---|---|---|---|---|
Active phase | PMS-1000 | Petrocol DH | Squalane | C78, Branched paraffin | Squalane |
Column length (m) | 2. | 150. | 93. | 3.3 | |
Carrier gas | N2 | H2 | He | He | |
Substrate | Chromaton N-AW-DMCS | ||||
Column diameter (mm) | 0.25 | 0.25 | |||
Phase thickness (μm) | 1. | ||||
Temperature (C) | 90. | 30. | 30. | 130. | 100. |
I | 786. | 788.3 | 780.4 | 784.9 | 783. |
Reference | Arutyunov, Kudryashov, et al., 2004 | Soják, Addová, et al., 2004 | Soják, Addová, et al., 2004 | Dallos, Sisak, et al., 2000 | Heinzen, Soares, et al., 1999 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Packed | Packed |
---|---|---|---|---|---|
Active phase | DB-1 | DB-1 | Squalane | C78, Branched paraffin | Apolane |
Column length (m) | 10. | 10. | 3.3 | 3.7 | |
Carrier gas | He | He | |||
Substrate | Chromosorb G HP | ||||
Column diameter (mm) | 0.25 | 0.25 | |||
Phase thickness (μm) | 0.25 | 0.25 | |||
Temperature (C) | 140. | 60. | 25. | 130. | 130. |
I | 789. | 788. | 780. | 785.3 | 786. |
Reference | Beens, Tijssen, et al., 1998 | Beens, Tijssen, et al., 1998 | Hilal, Carreira, et al., 1994 | Reddy, Dutoit, et al., 1992 | Dutoit, 1991 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Methyl Silicone | Methyl Silicone | OV-101 | OV-101 | OV-101 |
Column length (m) | 50. | 50. | |||
Carrier gas | |||||
Substrate | |||||
Column diameter (mm) | 0.20 | 0.20 | |||
Phase thickness (μm) | |||||
Temperature (C) | 40. | 80. | 40. | 60. | 80. |
I | 788. | 789. | 788. | 789. | 789. |
Reference | Takeda, 1991 | Takeda, 1991 | Laub and Purnell, 1988 | Laub and Purnell, 1988 | Laub and Purnell, 1988 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | OV-101 | OV-101 | Squalane | Squalane |
Column length (m) | 50. | 100. | 100. | 100. | 100. |
Carrier gas | He | N2 | N2 | N2 | N2 |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.27 | 0.27 | 0.25 | 0.25 |
Phase thickness (μm) | 0.9 | 0.9 | |||
Temperature (C) | 110. | 50. | 70. | 50. | 70. |
I | 789. | 788.3 | 789. | 781. | 781.8 |
Reference | Rang, Kuningas, et al., 1987 | Boneva and Dimov, 1986 | Boneva and Dimov, 1986 | Boneva and Dimov, 1986 | Boneva and Dimov, 1986 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Packed | Capillary | Capillary | Packed |
---|---|---|---|---|---|
Active phase | OV-1 | SE-30 | DB-1 | HP-PONA | SE-30 |
Column length (m) | 55. | 3. | 60. | 50. | 3. |
Carrier gas | N2 | H2 | H2 | Ar | |
Substrate | Gas Chrom Q (80-100 mesh) | ||||
Column diameter (mm) | 0.21 | 0.264 | 0.21 | ||
Phase thickness (μm) | 0.35 | 0.25 | 0.5 | ||
Temperature (C) | 100. | 42. | 40. | 40. | 150. |
I | 789.0 | 788. | 788. | 788. | 790. |
Reference | Anders, Anders, et al., 1985 | Rudenko, Mal'tsev, et al., 1985 | Lubeck and Sutton, 1984 | Lubeck and Sutton, 1984 | Tiess, 1984 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-3 | OV-3 | OV-3 | OV-3 | OV-3 |
Column length (m) | |||||
Carrier gas | |||||
Substrate | |||||
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Temperature (C) | 30. | 40. | 50. | 60. | 70. |
I | 792.5 | 792.6 | 792.7 | 792.8 | 792.9 |
Reference | Chien, Furio, et al., 1983 | Chien, Furio, et al., 1983 | Chien, Furio, et al., 1983 | Chien, Furio, et al., 1983 | Chien, Furio, et al., 1983 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Packed | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-3 | SE-30 | SE-30 | SE-30 | OV-1 |
Column length (m) | 2. | 100. | 100. | ||
Carrier gas | H2 | ||||
Substrate | Gaschrom Q | ||||
Column diameter (mm) | 0.5 | 0.5 | |||
Phase thickness (μm) | |||||
Temperature (C) | 80. | 100. | 130. | 80. | 30. |
I | 793.0 | 790. | 789. | 789. | 788.4 |
Reference | Chien, Furio, et al., 1983 | Winskowski, 1983 | Bredael, 1982 | Bredael, 1982 | Chien, Kopecni, et al., 1981 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-1 | OV-1 | OV-1 | OV-1 | OV-1 |
Column length (m) | |||||
Carrier gas | H2 | H2 | H2 | H2 | H2 |
Substrate | |||||
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Temperature (C) | 40. | 50. | 60. | 70. | 80. |
I | 788.6 | 788.8 | 789. | 786.7 | 789.4 |
Reference | Chien, Kopecni, et al., 1981 | Chien, Kopecni, et al., 1981 | Chien, Kopecni, et al., 1981 | Chien, Kopecni, et al., 1981 | Chien, Kopecni, et al., 1981 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | SE-30 | SE-30 | SE-30 | SE-30 |
Column length (m) | |||||
Carrier gas | H2 | H2 | H2 | H2 | H2 |
Substrate | |||||
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Temperature (C) | 30. | 40. | 50. | 60. | 70. |
I | 788.1 | 787.7 | 787.6 | 787.3 | 787. |
Reference | Chien, Kopecni, et al., 1981 | Chien, Kopecni, et al., 1981 | Chien, Kopecni, et al., 1981 | Chien, Kopecni, et al., 1981 | Chien, Kopecni, et al., 1981 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Packed | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | OV-1 | Squalane | Squalane | Squalane |
Column length (m) | 150. | 80. | |||
Carrier gas | H2 | He | |||
Substrate | |||||
Column diameter (mm) | 0.50 | 0.23 | |||
Phase thickness (μm) | |||||
Temperature (C) | 80. | 60. | 50. | 80. | 50. |
I | 786.6 | 790. | 781.6 | 782. | 781. |
Reference | Chien, Kopecni, et al., 1981 | Nijs and Jacobs, 1981 | Welsch, Engewald, et al., 1978 | Chrétien and Dubois, 1977 | Chretien and Dubois, 1976 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Packed | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Squalane | Squalane | Apolane | Squalane | Squalane |
Column length (m) | 120. | 120. | 2.4 | 50. | 50. |
Carrier gas | He | He | He | ||
Substrate | Chromosorb | ||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Phase thickness (μm) | |||||
Temperature (C) | 100. | 100. | 70. | 60. | 60. |
I | 782.6 | 784. | 783.7 | 782. | 782. |
Reference | Lulova, Leont'eva, et al., 1976 | Lulova, Leont'eva, et al., 1976 | Riedo, Fritz, et al., 1976 | Ryba, 1976 | Ryba, 1976 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Packed | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Squalane | Squalane | Squalane | Squalane | OV-101 |
Column length (m) | 120. | 1. | 100. | 100. | 25. |
Carrier gas | He | N2 | N2 | N2 | N2 |
Substrate | DCMS-treated Celite | ||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Phase thickness (μm) | 1.39 | ||||
Temperature (C) | 55. | 100. | 50. | 70. | 50. |
I | 784. | 784. | 781. | 782. | 788. |
Reference | Lulova, Leont'eva, et al., 1975 | Vernon and Edwards, 1975 | Rijks and Cramers, 1974 | Rijks and Cramers, 1974 | Pacáková, Hoch, et al., 1973 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | Squalane | Squalane | Squalane | Squalane |
Column length (m) | 25. | 100. | 100. | 100. | |
Carrier gas | N2 | ||||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Phase thickness (μm) | 1.39 | ||||
Temperature (C) | 60. | 80. | 80. | 80. | 100. |
I | 788. | 782.67 | 782.67 | 782.7 | 783. |
Reference | Pacáková, Hoch, et al., 1973 | Schomburg and Dielmann, 1973 | Schomburg and Dielmann, 1973, 2 | Schomburg and Dielmann, 1973, 2 | Sojak, Hrivnak, et al., 1973 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Squalane | Squalane | Apiezon L | Squalane | Squalane |
Column length (m) | 45. | 80. | 80. | ||
Carrier gas | |||||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | ||
Phase thickness (μm) | |||||
Temperature (C) | 115. | 86. | 100. | 80. | 80. |
I | 783. | 782. | 789.2 | 781.4 | 781. |
Reference | Sojak, Hrivnak, et al., 1973 | Sojak, Hrivnak, et al., 1973 | Eisen, Orav, et al., 1972 | Eisen, Orav, et al., 1972 | Orav and Eisen, 1972 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Packed | Packed |
---|---|---|---|---|---|
Active phase | Squalane | Squalane | Squalane | Apiezon L | Apiezon L |
Column length (m) | 200. | 200. | 91.4 | 2.3 | 2.3 |
Carrier gas | N2 | N2 | N2 | N2 | N2 |
Substrate | DCMS-treated Chromosorb W | DCMS-treated Chromosorb W | |||
Column diameter (mm) | 0.2 | 0.2 | 0.25 | ||
Phase thickness (μm) | |||||
Temperature (C) | 115. | 86. | 40. | 100. | 150. |
I | 782.9 | 782.3 | 783. | 786. | 790. |
Reference | Soják and Bucinská, 1970 | Soják and Bucinská, 1970 | Matukuma, 1969 | Brown, Chapman, et al., 1968 | Brown, Chapman, et al., 1968 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Packed | Packed |
---|---|---|---|
Active phase | Squalane | Apiezon L | Apiezon L |
Column length (m) | 100. | 2.25 | 2.25 |
Carrier gas | Ar | ||
Substrate | Celite | Celite | |
Column diameter (mm) | |||
Phase thickness (μm) | |||
Temperature (C) | 70. | 130. | 190. |
I | 782. | 783. | 779. |
Reference | Schomburg, 1967 | Wehrli and Kováts, 1959 | Wehrli and Kováts, 1959 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, isothermal, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Arutyunov, Kudryashov, et al., 2004
Arutyunov, Y.I.; Kudryashov, S.Y.; Onuchak, L.A.,
Analysis of Mixtures Containing Unknown Components by Gas Chromatography: Determination of Molecular Mass,
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Soják, Addová, et al., 2004
Soják, L.; Addová, G.; Kubinec, R.; Kraus, A.; Bohác, A.,
Capillary gas chromatography-mass spectrometry of all 93 acyclic octenes and their identification in fluid catalytic cracked gasoline,
J. Chromatogr. A, 2004, 1025, 2, 237-253, https://doi.org/10.1016/j.chroma.2003.10.112
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Dallos, Sisak, et al., 2000
Dallos, A.; Sisak, A.; Kulcsár, Z.; Kováts, E.,
Pair-wise interactions by gas chromatography VII. Interaction free enthalpies of solutes with secondary alcohol groups,
J. Chromatogr. A, 2000, 904, 2, 211-242, https://doi.org/10.1016/S0021-9673(00)00908-0
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Heinzen, Soares, et al., 1999
Heinzen, V.E.F.; Soares, M.F.; Yunes, R.A.,
Semi-empirical topological method for the prediction of the chromatographic retention of cis- and trans-alkene isomers and alkanes,
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Beens, Tijssen, et al., 1998
Beens, J.; Tijssen, R.; Blomberg, J.,
Prediction of comprehensive two-dimensional gas chromatographic separations. A theoretical and practical exercise,
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Hilal, Carreira, et al., 1994
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Estimation of Gas-Liquid Chromatographic Retention Times from Molecular Structure,
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Reddy, Dutoit, et al., 1992
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Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups,
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Dutoit, 1991
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Gas chromatographic retention behaviour of some solutes on structurally similar polar and non-polar stationary phases,
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Takeda, 1991
Takeda, I.,
Use of literature values of temperature programmed retention indexes in qualitative analysis by isothermal gas chromatography,
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Laub and Purnell, 1988
Laub, R.J.; Purnell, J.H.,
Specific retention volumes, retention indices, and family-plot regressions of aliphatic, alicyclic, and aromatic hydrocarbon solutes with OV-101 poly (dimethylsiloxane) stationary phase,
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Rang, Kuningas, et al., 1987
Rang, S.; Kuningas, K.; Strenze, T.; Orav, A.; Eisen, O.,
Retention and Thermodynamics of Solution of n-Alkenes in OV-101,
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Boneva and Dimov, 1986
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Gas Chromatographic Retention Indices for Alkenes on OV-101 and Squalane Capillary Columns,
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Anders, Anders, et al., 1985
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Identification of non-branched alkenylcycloalkanes with a terminal double bond from retention index increments,
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Rudenko, Mal'tsev, et al., 1985
Rudenko, G.I.; Mal'tsev, V.V.; Studenichnik, V.N.; Ustinov, E.P.,
Gas chromatographic analysis of volatile substances evolved into atmosphere from polymer materials,
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Lubeck and Sutton, 1984
Lubeck, A.J.; Sutton, D.L.,
Kovats Retention Indices of Selected Olefins on Bonded Phase Fused Silica Capillaries,
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Tiess, 1984
Tiess, D.,
Gaschromatographische Retentionsindices von 125 leicht- bis mittelflüchtigen organischen Substanzen toxikologisch-analytischer Relevanz auf SE-30,
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Chien, Furio, et al., 1983
Chien, C.-F.; Furio, D.L.; Kopecni, M.M.; Laub, R.J.,
Specific retention volumes and retention indices of selected hydrocarbon solutes with OV-3, OV-7, OV-11, OV-17, OV-22, and OV-25 polymethylphenylsiloxane solvents,
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Winskowski, 1983
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Gaschromatographische Identifizierung von Stoffen anhand von Indexziffem und unterschiedlichen Detektoren,
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Bredael, 1982
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Retention indices of hydrocarbons on SE-30,
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Chien, Kopecni, et al., 1981
Chien, C.-F.; Kopecni, M.M.; Laub, R.J.,
Specific Retention Volumes and Retention Indices of Selected Hydrocarbon Solutes with OV-1 and SE-30 Polydimethylsiloxane Solvents,
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On-Line Single Run Analysis of Effluents from a Fischer-Tropsch Reactor,
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Chretien, J.R.; Dubois, J.-E.,
New Perspectives in the Prediction of Kovats Indices,
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Lulova, Leont'eva, et al., 1976
Lulova, N.I.; Leont'eva, S.A.; Timofeeva, A.N.,
Gas-chromatographic method of determination of individual hydrocarbons in catalytic cracking gasolines
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Riedo, Fritz, et al., 1976
Riedo, F.; Fritz, D.; Tarján, G.; Kováts, E.Sz.,
A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography,
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Ryba, 1976
Ryba, M.,
Unlösliche Restfilme er stationären Flüssigkeit in gas-chromatographischen Glaskapillaren,
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Lulova, Leont'eva, et al., 1975
Lulova, N.I.; Leont'eva, S.A.; Fedosova, A.K.; Kvasova, V.A.,
Individual composition of hydrocarbons in naphthas from secondary processes,
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Vernon and Edwards, 1975
Vernon, F.; Edwards, G.T.,
Gas-liquid chromatography on fluorinated stationary phases. I. Hydrocarbons and fluorocarbons,
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Rijks and Cramers, 1974
Rijks, J.A.; Cramers, C.A.,
High precision capillary gas chromatography of hydrocarbons,
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Pacáková, Hoch, et al., 1973
Pacáková, V.; Hoch, K.; Smolková, E.,
The Effect of Instrumentation on the Precision of Retention Indexes,
Chromatographia, 1973, 6, 7, 320-324, https://doi.org/10.1007/BF02269334
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Schomburg and Dielmann, 1973
Schomburg, G.; Dielmann, G.,
Identification by means of retention parameters,
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Schomburg and Dielmann, 1973, 2
Schomburg, G.; Dielmann, G.,
Use of retention increments for identification and correlation of saturated and unsaturated cyclopropane hydrocarbons by means of Kovats indices,
Anal. Chem., 1973, 45, 9, 1647-1658, https://doi.org/10.1021/ac60331a021
. [all data]
Sojak, Hrivnak, et al., 1973
Sojak, L.; Hrivnak, J.; Majer, P.; Janak, J.,
Capillary Gas Chromatography of Linear Alkenes on Squalane,
Anal. Chem., 1973, 45, 2, 293-302, https://doi.org/10.1021/ac60324a039
. [all data]
Eisen, Orav, et al., 1972
Eisen, O.; Orav, A.; Rang, S.,
Identifizierung von Normal-Alkenen, Cyclopentenen und -Hexenen mittels Kapillar-Gas-Chromatographie. Identification des alcènes, cyclopentènes et -hexènes à l'aide de la chromatogrpahie en phase gazeuse sur colonne capillaire,
Chromatographia, 1972, 5, 11, 229-239, https://doi.org/10.1007/BF02270600
. [all data]
Orav and Eisen, 1972
Orav, A.; Eisen, O.,
The retention indexes for alkenes, alkynes and cyclenes on capillary columns,
Izv. Akad. Nauk Est. SSR, Khim. Geol., 1972, 21, 1, 39-47. [all data]
Soják and Bucinská, 1970
Soják, L.; Bucinská, A.,
Open tubular column gas chromatography of dehydrogenation products of C6-C10 n-alkanes. Separation and identification of mixtures of C6-C10 straight-chain alkanes, alkenes and aromatics,
J. Chromatogr., 1970, 51, 75-82, https://doi.org/10.1016/S0021-9673(01)96841-4
. [all data]
Matukuma, 1969
Matukuma, A.,
Retention indices of alkanes through C10 and alkenes through C8 and relation between boiling points and retention data,
Gas Chromatogr., Int. Symp. Anal. Instrum. Div Instrum Soc. Amer., 1969, 7, 55-75. [all data]
Brown, Chapman, et al., 1968
Brown, I.; Chapman, I.L.; Nicholson, G.J.,
Gas chromatography of polar solutes in electron acceptor stationary phases,
Aust. J. Chem., 1968, 21, 5, 1125-1141, https://doi.org/10.1071/CH9681125
. [all data]
Schomburg, 1967
Schomburg, G.,
Struktur und Retentionsverhalten von Offenkettigen und Cyclischen Kohlenwasserstoffen und Deren Einfacher Substitutionsprodukte,
Anal. Chim. Acta., 1967, 38, 45-64, https://doi.org/10.1016/S0003-2670(01)80560-2
. [all data]
Wehrli and Kováts, 1959
Wehrli, A.; Kováts, E.,
Gas-chromatographische Charakterisierung ogranischer Verbindungen. Teil 3: Berechnung der Retentionsindices aliphatischer, alicyclischer und aromatischer Verbindungen,
Helv. Chim. Acta, 1959, 7, 7, 2709-2736, https://doi.org/10.1002/hlca.19590420745
. [all data]
Notes
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