Propyl sulfide
- Formula: C6H14S
- Molecular weight: 118.240
- IUPAC Standard InChI: InChI=1S/C6H14S/c1-3-5-7-6-4-2/h3-6H2,1-2H3
- IUPAC Standard InChIKey: ZERULLAPCVRMCO-UHFFFAOYSA-N
- CAS Registry Number: 111-47-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Propane, 1,1'-thiobis-; Dipropyl sulfide; Dipropyl thioether; Propyl monosulfide; 4-Thiaheptane; 1,1'-Thiobispropane; Dipropyl sulphide; (n-C3H7)2S; n-Propyl sulfide; di-n-Propyl sulfide; Di-n-propyl thioether; NSC 78429; Sulfide, n-propyl-
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -169.8 ± 0.88 | kJ/mol | Ccr | McCullough, Finke, et al., 1961 | ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -4794.28 ± 0.75 | kJ/mol | Ccr | McCullough, Finke, et al., 1961 | Reanalyzed by Cox and Pilcher, 1970, Original value = -4793.78 ± 0.75 kJ/mol; ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| S°liquid | 338.28 | J/mol*K | N/A | McCullough, Finke, et al., 1961 | DH |
Constant pressure heat capacity of liquid
| Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 237.90 | 300. | Tutubalina, Gabdrakhmanov, et al., 1982 | T = 273 to 373 K. Cp = 221.21 + 3.060x10-2T + 8.343x10-5T2.; DH |
| 225.48 | 298.15 | McCullough, Finke, et al., 1961 | T = 11 to 370 K.; DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
McCullough, Finke, et al., 1961
McCullough, J.P.; Finke, H.L.; Hubbard, W.N.; Todd, S.S.; Messerly, J.F.; Douslin, D.R.; Waddington, G.,
Thermodynamic properties of four linear thiaalkanes,
J. Phys. Chem., 1961, 65, 784-791. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Tutubalina, Gabdrakhmanov, et al., 1982
Tutubalina, V.P.; Gabdrakhmanov, F.G.; Konyukhova, T.M.,
Study of the heat capacity of n-sulfides, 1982, Teplo-Massoobmen Khim. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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