Ethanol, 2,2'-oxybis-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-150.22 ± 0.57kcal/molCcbMoureu and Dode, 1937Reanalyzed by Cox and Pilcher, 1970, Original value = -150.1 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Δcliquid-567.56 ± 0.57kcal/molCcbMoureu and Dode, 1937Reanalyzed by Cox and Pilcher, 1970, Original value = -567.9 kcal/mol; Corresponding Δfliquid = -150.22 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-567.14kcal/molCcbRinkenbach, 1927Corresponding Δfliquid = -150.6 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
58.29298.Zaripov, 1982T = 298, 323, 363 K.; DH
68.59298.Stephens and Tamplin, 1979T = 273 to 513 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Ethanol, 2,2'-oxybis- + Nitric acid = Ethanol, 2-(2-hydroxyethoxy)-, 1-nitrate + Water

By formula: C4H10O3 + HNO3 = C4H9NO5 + H2O

Quantity Value Units Method Reference Comment
Δr-2.1kcal/molCmTsvetkov, Sopin, et al., 1986liquid phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Moureu and Dode, 1937
Moureu, H.; Dode, M., Chaleurs de formation de l'oxyde d'ethylene, de l'ethanediol et de quelques homologues, Bull. Soc. Chim. France, 1937, 4, 637-647. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Rinkenbach, 1927
Rinkenbach, Wm.H., Properties of Diethylene Glycol, Ind. Eng. Chem., 1927, 19, 474-475. [all data]

Zaripov, 1982
Zaripov, Z.I., Experimental study of the isobaric heat capacity of liquid organic compounds with molecular weights of up to 4000 a.e.m., 1982, Teplomassoobmen Teplofiz. [all data]

Stephens and Tamplin, 1979
Stephens, M.A.; Tamplin, W.S., Saturated liquid specific heats of ethylene glycol homologues, J. Chem. Eng. Data, 1979, 24, 81-82. [all data]

Tsvetkov, Sopin, et al., 1986
Tsvetkov, V.G.; Sopin, V.P.; Tsvetkova, L.Ya.; Marchenko, G.N., Enthalpy of reaction of nitric acid with some organic compounds, J. Gen. Chem. USSR, 1986, 56, 471-474. [all data]


Notes

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