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1-(Dimethoxy-phenylmethyl)-1H-imidazole


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

1-(Dimethoxy-phenylmethyl)-1H-imidazole + Water = 1H-Imidazole + Methyl Alcohol + Benzoic acid, methyl ester

By formula: C12H14N2O2 + H2O = C3H4N2 + CH4O + C8H8O2

Quantity Value Units Method Reference Comment
Deltar-55.48 ± 0.71kJ/molCmGuthrie and Pike, 1987liquid phase; Heat of hydrolysis

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Guthrie and Pike, 1987
Guthrie, J.P.; Pike, D.C., Hydration of acylimidazoles: tetrahedral intermediates in acylimidazole hydrolysis and nucleophilic attack by imidazole on esters. The question of concerted mechanisms for acyl transfers, Can. J. Chem., 1987, 65, 1951-1969. [all data]


Notes

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