Butane, 1-(ethenyloxy)-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfgas-179.2 ± 1.2kJ/molCcrSteele, Chirico, et al., 1996ALS
Δfgas-182.4kJ/molN/ATrofimov, Nedolya, et al., 1981Value computed using ΔfHliquid° value of -219.0±0.8 kj/mol from Trofimov, Nedolya, et al., 1981 and ΔvapH° value of 36.6 kj/mol from Steele, Chirico, et al., 1996.; DRB

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-215.8 ± 1.2kJ/molCcrSteele, Chirico, et al., 1996ALS
Δfliquid-219. ± 0.8kJ/molCcbTrofimov, Nedolya, et al., 1981ALS
Quantity Value Units Method Reference Comment
Δcliquid-3860.2 ± 1.1kJ/molCcrSteele, Chirico, et al., 1996Corresponding Δfliquid = -215.84 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-3857. ± 0.8kJ/molCcbTrofimov, Nedolya, et al., 1981Corresponding Δfliquid = -219. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
231.8298.15Schildknecht, Zoss, et al., 1947One value, no details.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil367.0KN/AWeast and Grasselli, 1989BS
Tboil366.KN/AAmerican Tokyo Kasei, 1988BS
Tboil367.1KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Tc540.5KN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Pc32.00barN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 2.50 bar; from extraploation of obs. vapor pressures to Tc; TRC
Quantity Value Units Method Reference Comment
ρc2.607mol/lN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 0.12 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap36. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
31.58367.1N/AMajer and Svoboda, 1985 
35.2 ± 0.2320.EBSteele, Chirico, et al., 1996Based on data from 311. to 403. K.; AC
32.5 ± 0.2360.EBSteele, Chirico, et al., 1996Based on data from 311. to 403. K.; AC
29.6 ± 0.2400.EBSteele, Chirico, et al., 1996Based on data from 311. to 403. K.; AC
36.1284.AStephenson and Malanowski, 1987Based on data from 269. to 368. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Chirico, et al., 1996
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Smith, N.K., Thermodynamic properties and ideal-gas enthalpies of formation for butyl vinyl ether, 1,2-dimethoxyethane, methyl glycolate, bicyclo[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, di-tert-butyl ether, and hexane-1,6-diol, J. Chem. Eng. Data, 1996, 41, 1285-1302. [all data]

Trofimov, Nedolya, et al., 1981
Trofimov, B.A.; Nedolya, N.A.; Lebedeva, N.D.; Ryadchenko, V.L.; Masalitionova, T.N.; Dobichin, S.L.; Zacheslavskaya, R.Kh.; Petrov, G.N., Thermochemical and quantochemical estimationof the conjungation energy of vinyl ethers., Izv. Akad. Nauk SSSR, Ser. Khim., 1981, 30, 752-753. [all data]

Schildknecht, Zoss, et al., 1947
Schildknecht, C.E.; Zoss, A.O.; McKinley, C., Vinyl alkyl ethers, Ind. Eng. Chem., 1947, 39, 180-186. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

American Tokyo Kasei, 1988
American Tokyo Kasei, TCI American Organic Chemical 88/89 Catalog, American Tokyo Kasei, Portland, OR, 1988, 1610. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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