Butane, 1-(ethenyloxy)-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfgas-42.83 ± 0.29kcal/molCcrSteele, Chirico, et al., 1996ALS
Δfgas-43.59kcal/molN/ATrofimov, Nedolya, et al., 1981Value computed using ΔfHliquid° value of -219.0±0.8 kj/mol from Trofimov, Nedolya, et al., 1981 and ΔvapH° value of 36.6 kj/mol from Steele, Chirico, et al., 1996.; DRB

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-51.59 ± 0.28kcal/molCcrSteele, Chirico, et al., 1996ALS
Δfliquid-52.3 ± 0.2kcal/molCcbTrofimov, Nedolya, et al., 1981ALS
Quantity Value Units Method Reference Comment
Δcliquid-922.61 ± 0.27kcal/molCcrSteele, Chirico, et al., 1996Corresponding Δfliquid = -51.587 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-921.9 ± 0.2kcal/molCcbTrofimov, Nedolya, et al., 1981Corresponding Δfliquid = -52.3 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
55.40298.15Schildknecht, Zoss, et al., 1947One value, no details.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil367.0KN/AWeast and Grasselli, 1989BS
Tboil366.KN/AAmerican Tokyo Kasei, 1988BS
Tboil367.1KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Tc540.5KN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Pc31.58atmN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 2.47 atm; from extraploation of obs. vapor pressures to Tc; TRC
Quantity Value Units Method Reference Comment
ρc2.607mol/lN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 0.12 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap8.6 ± 0.4kcal/molAVGN/AAverage of 6 values; Individual data points

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
7.548367.1N/AMajer and Svoboda, 1985 
8.41 ± 0.05320.EBSteele, Chirico, et al., 1996Based on data from 311. to 403. K.; AC
7.77 ± 0.05360.EBSteele, Chirico, et al., 1996Based on data from 311. to 403. K.; AC
7.07 ± 0.05400.EBSteele, Chirico, et al., 1996Based on data from 311. to 403. K.; AC
8.63284.AStephenson and Malanowski, 1987Based on data from 269. to 368. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
PackedSE-30120.695.García-Raso, Martínez-Castro, et al., 1987N2, Supelcoport; Column length: 3. m
PackedApiezon L120.671.Bogoslovsky, Anvaer, et al., 1978Celite 545
PackedApiezon L160.679.Bogoslovsky, Anvaer, et al., 1978Celite 545

Kovats' RI, polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryCarbowax 20M120.858.García-Raso, Martínez-Castro, et al., 1987N2, Supelcoport; Column length: 25. m; Column diameter: 0.22 mm

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryOV-101687.Zenkevich, 200525. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillarySqualane695.Chen, 2008Program: not specified

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Chirico, et al., 1996
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Smith, N.K., Thermodynamic properties and ideal-gas enthalpies of formation for butyl vinyl ether, 1,2-dimethoxyethane, methyl glycolate, bicyclo[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, di-tert-butyl ether, and hexane-1,6-diol, J. Chem. Eng. Data, 1996, 41, 1285-1302. [all data]

Trofimov, Nedolya, et al., 1981
Trofimov, B.A.; Nedolya, N.A.; Lebedeva, N.D.; Ryadchenko, V.L.; Masalitionova, T.N.; Dobichin, S.L.; Zacheslavskaya, R.Kh.; Petrov, G.N., Thermochemical and quantochemical estimationof the conjungation energy of vinyl ethers., Izv. Akad. Nauk SSSR, Ser. Khim., 1981, 30, 752-753. [all data]

Schildknecht, Zoss, et al., 1947
Schildknecht, C.E.; Zoss, A.O.; McKinley, C., Vinyl alkyl ethers, Ind. Eng. Chem., 1947, 39, 180-186. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

American Tokyo Kasei, 1988
American Tokyo Kasei, TCI American Organic Chemical 88/89 Catalog, American Tokyo Kasei, Portland, OR, 1988, 1610. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

García-Raso, Martínez-Castro, et al., 1987
García-Raso, A.; Martínez-Castro, I.; Páez, M.I.; Sanz, J.; García-Raso, J.; Saura-Calixto, F., Gas Chromatographic Behaviour of Carbohydrate Trimethylsilyl Ethers. I. Aldopentoses, J. Chromatogr., 1987, 398, 9-20, https://doi.org/10.1016/S0021-9673(01)96491-X . [all data]

Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S., Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]

Zenkevich, 2005
Zenkevich, I.G., Experimentally measured retention indices., 2005. [all data]

Chen, 2008
Chen, H.-F., Quantitative prediction of gas chromatography retention indices with support vector machines, radial basis neutral networks and multiple linear regression, Anal. Chim. Acta, 2008, 609, 1, 24-36, https://doi.org/10.1016/j.aca.2008.01.003 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, References