1-Hexanol
- Formula: C6H14O
- Molecular weight: 102.1748
- IUPAC Standard InChI: InChI=1S/C6H14O/c1-2-3-4-5-6-7/h7H,2-6H2,1H3
- IUPAC Standard InChIKey: ZSIAUFGUXNUGDI-UHFFFAOYSA-N
- CAS Registry Number: 111-27-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Hexyl alcohol; n-Hexan-1-ol; n-Hexanol; n-Hexyl alcohol; Amylcarbinol; Caproyl alcohol; Hexanol; Pentylcarbinol; 1-Hexyl alcohol; 1-Hydroxyhexane; n-C6H13OH; Hexan-1-ol; Hexanol-(1); Epal 6; NSC 9254
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Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
| ΔvapH° (kJ/mol) | Method | Reference | Comment |
|---|---|---|---|
| 61.61 | N/A | Majer and Svoboda, 1985 | |
| 59.1 | N/A | Schmeling and Strey, 2010 | Based on data from 243. to 303. K.; AC |
| 59.9 | N/A | Nasirzadeh, Neueder, et al., 2006 | Based on data from 328. to 423. K.; AC |
| 61.7 ± 0.3 | GS | Roganov, Pisarev, et al., 2005 | Based on data from 265. to 363. K.; AC |
| 61.1 | GS | Kulikov, Verevkin, et al., 2001 | Based on data from 265. to 328. K.; AC |
| 62.1 ± 0.2 | GS | Verevkin, 1998 | Based on data from 268. to 333. K.; AC |
| 61.5 | CGC | Chickos, Hosseini, et al., 1995 | Based on data from 373. to 423. K.; AC |
| 61.6 | CGC | Chickos, Hosseini, et al., 1995 | Based on data from 323. to 373. K.; AC |
| 61.85 ± 0.20 | C | Mansson, Sellers, et al., 1977 | ALS |
| 60.8 ± 0.2 | C | Månsson, Sellers, et al., 1977 | AC |
| 61.6 ± 0.2 | C | Wadsö, Murto, et al., 1966 | AC |
| 61.6 ± 0.2 | C | Wadso, 1966 | ALS |
| 62.8 ± 1.3 | V | Green, 1960 | ALS |
| 69.2 | N/A | Green, 1960 | DRB; Data excluded from overall average |
References
Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Schmeling and Strey, 2010
Schmeling, T.; Strey, K.,
Equilibrium Vapor Pressure Measurements for the n-Alcohols in the Temperature Range from -30 °C to + 30 °C,
Berichte der Bunsengesellschaft für physikalische Chemie, 2010, 87, 10, 871-874, https://doi.org/10.1002/bbpc.19830871008
. [all data]
Nasirzadeh, Neueder, et al., 2006
Nasirzadeh, Karamat; Neueder, Roland; Kunz, Werner,
Vapor Pressure Determination of the Aliphatic C 5 to C 8 1-Alcohols,
J. Chem. Eng. Data, 2006, 51, 1, 7-10, https://doi.org/10.1021/je049600u
. [all data]
Roganov, Pisarev, et al., 2005
Roganov, Gennady N.; Pisarev, Pavel N.; Emel'yanenko, Vladimir N.; Verevkin, Sergey P.,
Measurement and Prediction of Thermochemical Properties. Improved Benson-Type Increments for the Estimation of Enthalpies of Vaporization and Standard Enthalpies of Formation of Aliphatic Alcohols,
J. Chem. Eng. Data, 2005, 50, 4, 1114-1124, https://doi.org/10.1021/je049561m
. [all data]
Kulikov, Verevkin, et al., 2001
Kulikov, Dmitry; Verevkin, Sergey P.; Heintz, Andreas,
Enthalpies of vaporization of a series of aliphatic alcohols,
Fluid Phase Equilibria, 2001, 192, 1-2, 187-207, https://doi.org/10.1016/S0378-3812(01)00633-1
. [all data]
Verevkin, 1998
Verevkin, Sergey P.,
Thermochemistry of phenols: experimental standard molar enthalpies of formation of 2-phenylphenol, 4-phenylphenol, 2,6-diphenylphenol, and 2,2´- and 4,4´-dihydroxybiphenyl,
The Journal of Chemical Thermodynamics, 1998, 30, 3, 389-396, https://doi.org/10.1006/jcht.1997.0316
. [all data]
Chickos, Hosseini, et al., 1995
Chickos, James S.; Hosseini, Sarah; Hesse, Donald G.,
Determination of vaporization enthalpies of simple organic molecules by correlations of changes in gas chromatographic net retention times,
Thermochimica Acta, 1995, 249, 41-62, https://doi.org/10.1016/0040-6031(95)90670-3
. [all data]
Mansson, Sellers, et al., 1977
Mansson, M.; Sellers, P.; Stridh, G.; Sunner, S.,
Enthalpies of vaporization of some 1-substituted n-alkanes,
J. Chem. Thermodyn., 1977, 9, 91. [all data]
Månsson, Sellers, et al., 1977
Månsson, M.; Sellers, P.; Stridh, G.; Sunner, S.,
Enthalpies of vaporization of some 1-substituted n-alkanes,
The Journal of Chemical Thermodynamics, 1977, 9, 1, 91-97, https://doi.org/10.1016/0021-9614(77)90202-6
. [all data]
Wadsö, Murto, et al., 1966
Wadsö, Ingemar; Murto, Maija-Leena; Bergson, Göran; Ehrenberg, L.; Brunvoll, J.; Bunnenberg, E.; Djerassi, Carl; Records, Ruth,
Heats of Vaporization for a Number of Organic Compounds at 25 degrees C.,
Acta Chem. Scand., 1966, 20, 544-552, https://doi.org/10.3891/acta.chem.scand.20-0544
. [all data]
Wadso, 1966
Wadso, I.,
Acta Chem. Scand., 1966, 20, 544. [all data]
Green, 1960
Green, J.H.S.,
Revision of the values of the heats of formation of normal alcohols,
Chem. Ind. (London), 1960, 1215-1216. [all data]
Notes
Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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