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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δcliquid-3440.kJ/molCcbHandrick, 1956W. R. Tomlinson 1949
Δcliquid-3500.4kJ/molCcbCastronia, 1949 
Quantity Value Units Method Reference Comment
Δfsolid-656.9kJ/molCcrBaroody and Carpenter, 1972 
Δfsolid-603.8kJ/molCcbTavernier, 1956 

Phase change data

Go To: Top, Condensed phase thermochemistry data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap88.4 ± 0.1kJ/molVWoodman and Adicoff, 1963ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
88.3318.AStephenson and Malanowski, 1987Based on data from 303. to 348. K. See also Dykyj, 1972 and Woodman and Adicoff, 1963.; AC

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
PackedOV-1011595.Alley and Dykes, 19726. K/min; Tstart: 70. C; Tend: 220. C

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Handrick, 1956
Handrick, G.R., Report of the study of pure explosive compounds. Part IV. Calculation of heat of combustion of organic compounds from structural features and calculation of power of high explosives, Rpt. C-58247 for the Office of the Chief of Ordnance, contract DA-19-020-ORD-47 by the Arthur D. Little, Inc., Cambridge, MA, 1956, 467-573. [all data]

Castronia, 1949
Castronia, T.C., Long range basic research leading to the development of ideal propellants, Picatinny Arsenal Techn. Rep. No. 1755, 1949, 1. [all data]

Baroody and Carpenter, 1972
Baroody, E.E.; Carpenter, G.A., Heats of formation of propellant compounds (U), Rpt. Naval Ordnance Systems Command Task No. 331-003/067-1/UR2402-001 for Naval Ordance Station, Indian Head, MD, 1972, 1-9. [all data]

Tavernier, 1956
Tavernier, P., Donnees thermochimiques relatives aux constituants des poudres, Mem. Poudres, 1956, 301-327. [all data]

Woodman and Adicoff, 1963
Woodman, A.L.; Adicoff, A., Vapor pressure of triacetin, triethylene glycol dinitrte, and metriol trinitrate, J. Chem. Eng. Data, 1963, 8, 241-242. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Alley and Dykes, 1972
Alley, B.J.; Dykes, H.W.H., Gas-Liquid Chromatographic Determination of Nitrate Esters,Stabilizers and Plasticizers in Nitrocellulose-Base Propellants, J. Chromatogr., 1972, 71, 1, 23-37, https://doi.org/10.1016/S0021-9673(01)85687-9 . [all data]


Notes

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