1,3,5-Trioxane

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Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

ΔsubH° (kJ/mol) Method Reference Comment
55.6N/ADe Wit, Van Miltenburg, et al., 1983AC
56.5CBogdanova, Berlin, et al., 1975AC
56.6 ± 0.2CMansson, Morawetz, et al., 1969ALS
56.5N/AMansson, Morawetz, et al., 1969DRB
56.2 ± 0.2CMansson, Morawetz, et al., 1969See also Pedley and Rylance, 1977.; AC
48.5 ± 2.5VWalker and Carlisle, 1943ALS

References

Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

De Wit, Van Miltenburg, et al., 1983
De Wit, H.G.M.; Van Miltenburg, J.C.; De Kruif, C.G., Thermodynamic properties of molecular organic crystals containing nitrogen, oxygen, and sulphur 1. Vapour pressures and enthalpies of sublimation, The Journal of Chemical Thermodynamics, 1983, 15, 7, 651-663, https://doi.org/10.1016/0021-9614(83)90079-4 . [all data]

Bogdanova, Berlin, et al., 1975
Bogdanova, K.A.; Berlin, A.A.; Kompanets, V.Z.; Rakova, G.V.; Miroshnichenko, E.A.; Lebedev, Yu.A.; Enikolopyan, N.S., Vysokomol. Soed. A, 1975, 17, 3, 658. [all data]

Mansson, Morawetz, et al., 1969
Mansson, M.; Morawetz, E.; Nakase, Y.; Sunner, S., The enthalpies of formation of trioxane and tetroxane, Acta Chem. Scand., 1969, 23, 56-60. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., , Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]

Walker and Carlisle, 1943
Walker, J.F.; Carlisle, P.J., Trioxane, Chem. Eng. News, 1943, 21, 1250-1251. [all data]


Notes

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