Al5

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 17710 ± 650 gas Geske, Boldyrev, et al., 2000

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 14160 ± 330 gas Geske, Boldyrev, et al., 2000

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 5240 ± 180 gas Geske, Boldyrev, et al., 2000

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 2860 ± 140 gas Geske, Boldyrev, et al., 2000

Additional references: Jacox, 2003, page 278

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Geske, Boldyrev, et al., 2000
Geske, G.D.; Boldyrev, A.I.; Li, X.; Wang, L.-S., On the origin of planarity in Al[sub 5][sup -] and Al[sub 5] clusters: The importance of a four-center peripheral bond, J. Chem. Phys., 2000, 113, 13, 5130, https://doi.org/10.1063/1.1311966 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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