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1,4-Butanediol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - R.L. Brown and S.E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, M. Frenkel director
AC - W.E. Acree, Jr., J.S. Chickos
DRB - D.R. Burgess
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
DH - E.S. Domalski and E.D. Hearing

Quantity Value Units Method Reference Comment
Tboil503.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil502.88KN/AMarkovnik, Sachek, et al., 1981Uncertainty assigned by TRC = 0.05 K; TRC
Tboil501.15KN/AMellan, 1962Uncertainty assigned by TRC = 2. K; TRC
Tboil503.15KN/AMellan, 1962Uncertainty assigned by TRC = 2. K; TRC
Tboil501.15KN/AClendenning, Macdonald, et al., 1950Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Tfus300. ± 40.KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple289.9KN/AKnauth and Sabbah, 1990Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple293.58KN/AVasil'ev and Petrov, 1984Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple293.38KN/ANistratov, Babinkov, et al., 1979Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple293.58KN/ANistratov, Babinkov, et al., 1979Uncertainty assigned by TRC = 0.05 K; TRC
Quantity Value Units Method Reference Comment
Tc727.KN/AWilson, Wilson, et al., 1996Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Pc62.20barN/AWilson, Wilson, et al., 1996Uncertainty assigned by TRC = 1.50 bar; TRC
Quantity Value Units Method Reference Comment
Deltavap78. ± 3.kJ/molAVGN/AAverage of 8 values; Individual data points

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
393.20.013Weast and Grasselli, 1989BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
72.395.AStephenson and Malanowski, 1987Based on data from 380. - 510. K.; AC
77. ± 2.419.VGardner and Hussain, 1972ALS

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
18.700293.58Nistratov, Babinkov, et al., 1979, 2DH
18.7293.6Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
63.72293.58Nistratov, Babinkov, et al., 1979, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Markovnik, Sachek, et al., 1981
Markovnik, V.S.; Sachek, A.I.; Peshchenko, A.D.; Shvaro, O.V.; Andreyevskii, D.N., Vapor pressure of some glycols in Terodinamika Organ. Soedinenii., Gorkii, p 54, 1981. [all data]

Mellan, 1962
Mellan, I., Polyhydric Alcohols, Spartan Books: Washington, DC, 1962. [all data]

Clendenning, Macdonald, et al., 1950
Clendenning, K.A.; Macdonald, F.J.; Wright, D.E., Effects of position isomerism on the physical properties of glycols, Can. J. Res., Sect. B, 1950, 28, 608-22. [all data]

Knauth and Sabbah, 1990
Knauth, P.; Sabbah, R., Can. J. Chem., 1990, 68, 731. [all data]

Vasil'ev and Petrov, 1984
Vasil'ev, I.A.; Petrov, V.M., Thermodynamic Properties of Oxygen-containing Organic Compounds, Handbook, Soedinenii: Khimya, Leningrad, p 240, 1984. [all data]

Nistratov, Babinkov, et al., 1979
Nistratov, V.P.; Babinkov, A.G.; Shvetsova, K.G.; Kapteva, S.A., Heat capacity and thermodynamic functions of tetramethylene glycol., Termodin. Org. Soedin., 1979, No. 8, 33. [all data]

Wilson, Wilson, et al., 1996
Wilson, L.C.; Wilson, H.L.; Wilding, W.V.; Wilson, G.M., Critical Point Measurements for Fourteen Compounds by a Static Method and a Flow Method, J. Chem. Eng. Data, 1996, 41, 1252-4. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Gardner and Hussain, 1972
Gardner, P.J.; Hussain, K.S., The standard enthalpies of formation of some aliphatic diols, J. Chem. Thermodyn., 1972, 4, 819-827. [all data]

Nistratov, Babinkov, et al., 1979, 2
Nistratov, V.P.; Babinkov, A.G.; Shvetsova, K.G.; Lapteva, S.A., Heat capacity and termodynamic functions of tetramethyleneglycol, Termodin. Org. Soedin., 1979, (8), 33-36. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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