2-Butene, 1,4-dichloro-, (E)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
348.20.053Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
45.6355.AStephenson and Malanowski, 1987Based on data from 340. to 379. K.; AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2-Butene, 1,4-dichloro-, (Z)- = 2-Butene, 1,4-dichloro-, (E)-

By formula: C4H6Cl2 = C4H6Cl2

Quantity Value Units Method Reference Comment
Δr-0.71kJ/molEqkZakharova, Gul'neva, et al., 1991gas phase; Heat of isomerization at 383 K

2-Butene, 1,4-dichloro-, (E)- = 2-Butene, 1,4-dichloro-, (Z)-

By formula: C4H6Cl2 = C4H6Cl2

Quantity Value Units Method Reference Comment
Δr-4.2kJ/molEqkLevanova, Yanshevskaya, et al., 1986liquid phase; solvent: Naphtha

2-Butene, 1,4-dichloro-, (E)- = 1-Butene, 3,4-dichloro-

By formula: C4H6Cl2 = C4H6Cl2

Quantity Value Units Method Reference Comment
Δr6.3kJ/molEqkLevanova, Yanshevskaya, et al., 1986liquid phase; solvent: Naphta

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Zakharova, Gul'neva, et al., 1991
Zakharova, L.A.; Gul'neva, I.V.; Shestakov, G.K.; Temkin, O.N.; Levanova, S.V.; Martirosyan, G.T.; Malkhasyan, A.Ts.; Asatryan, E.M., Isomerization of dichlorobutenes, Kinet. Catal., 1991, 32, 1190-1194, In original 1332. [all data]

Levanova, Yanshevskaya, et al., 1986
Levanova, S.V.; Yanshevskaya, I.V.; Asatryan, E.M.; Saakyan, N.L.; Kostand'yan, V.A.; Malkhasyan, A.Ts.; Martirosyan, G.T., Relationships of isomerization of the allylic type, J. Appl. Chem. USSR, 1986, 59, 790-793. [all data]


Notes

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