n-Hexane

• Formula: C₆H₁₄
• Molecular weight: 86.1754
• IUPAC Standard InChI: InChI=1S/C6H14/c1-3-5-6-4-2/h3-6H2,1-2H3 Copy

  
• IUPAC Standard InChIKey: VLKZOEOYAKHREP-UHFFFAOYSA-N Copy
• CAS Registry Number: 110-54-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Isotopologues:
  • Hexane-d14
  • Hexane-d7
• Other names: Hexane; Skellysolve B; n-C6H14; Esani; Heksan; Hexanen; Hexyl hydride; Gettysolve-B; NCI-C60571; NSC 68472
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Normal melting point
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Henry's Law data
  • Gas phase ion energetics data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Fluid Properties
• Data at other public NIST sites:
  • Computational Chemistry Comparison and Benchmark Database
  • Gas Phase Kinetics Database
• Options:
  • Switch to calorie-based units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, "lite" edition (thermophysical and thermochemical data)
• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Normal melting point

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

References

Go To: Top, Normal melting point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ait-Kaci and Merlin, 1979
Ait-Kaci, A.; Merlin, J.C., Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1979, No. 1, 67. [all data]

Carruth and Kobayashi, 1973
Carruth, G.F.; Kobayashi, R., Vapor pressure of normal paraffins ethane through n-decane from their triple points to about 10 mm Hg, J. Chem. Eng. Data, 1973, 18, 115-26. [all data]

Anonymous, 1951
Anonymous, R., , Sunbury Rep. No. 4199, Anglo-Iranian Oil Co., 1951. [all data]

Tilicheev, Peshkov, et al., 1951
Tilicheev, M.D.; Peshkov, V.P.; Yuganova, S.A., Cryoscopic Constants and Transition Temperatures of Normal Alkanes, Zh. Obshch. Khim., 1951, 21, 1229-37. [all data]

Anonymous, 1949
Anonymous, R., , Am. Pet. Inst. Res. Proj. 45, Ohio State Univ., 1949. [all data]

Boord, Henne, et al., 1949
Boord, C.E.; Henne, A.L.; Greenlee, K.W.; Perilstein, W.L.; Derfer, J.M., The Grignard Reagent in hydrocarbon synthesis, Ind. Eng. Chem., 1949, 41, 609. [all data]

Denyer, Fidler, et al., 1949
Denyer, R.L.; Fidler, F.A.; Lowry, R.A., Azeotrope Formation Between Thiols and Hydrocarbons, Ind. Eng. Chem., 1949, 41, 2727-37. [all data]

Dreisbach and Martin, 1949
Dreisbach, R.R.; Martin, R.A., Physical Data on Some Organic Compounds, Ind. Eng. Chem., 1949, 41, 2875-8. [all data]

Foehr and Fenske, 1949
Foehr, E.G.; Fenske, M.R., Magneto-optic Rotation of Hydrocarbons, Ind. Eng. Chem., 1949, 41, 1956. [all data]

Giller and Drickamer, 1949
Giller, E.B.; Drickamer, H.G., Viscosity of Normal Paraffins near the Freezing Point, Ind. Eng. Chem., 1949, 41, 2067. [all data]

Streiff and Rossini, 1948
Streiff, A.J.; Rossini, F.D., Unpublished, 1948. [all data]

Boord, Greenlee, et al., 1946
Boord, C.E.; Greenlee, K.W.; Perilstein, W.L., The Synthesis, Purification and Prop. of Hydrocarbons of Low Mol. Weight, Am. Pet. Inst. Res. Proj. 45, Eighth Annu. Rep., Ohio State Univ., June 30, 1946. [all data]

Forziati, Glasgow, et al., 1946
Forziati, A.F.; Glasgow, A.R.; Willingham, C.B.; Rossini, F.D., Specification adn Properties of 29 Paraffin, 4 Alkylcyclopentanes, 10 Alkylcyclohexanes and 8 Alkylbenzene Hydrocarbons, J. Res. Natl. Bur. Stand. (U. S.), 1946, 36, 129. [all data]

Glasgow, Murphy, et al., 1946
Glasgow, A.R.; Murphy, E.T.; Willingham, C.B.; Rossini, F.D., Purification, purity, and freezing points of 31 hydrocarbons of the api- nbs series, J. Res. Natl. Bur. Stand. (U. S.), 1946, 37, 141. [all data]

Anonymous, 1941
Anonymous, R., , Am. Pet. Inst. Hydrocarbon Res. Proj., Third Annu. Rep., Ohio State Univ., Aug. 31, 1941. [all data]

Campbell and Eby, 1941
Campbell, K.N.; Eby, L.T., The Reduction of Multiple Carbon-Carbon Bonds III. Further Studies on the Preparation of Olefins from Acetylenes, J. Am. Chem. Soc., 1941, 63, 2683. [all data]

Wibaut, Hoog, et al., 1939
Wibaut, J.P.; Hoog, H.; Langedijk, S.L.; Overhoff, J.; Smittenberg, J.; Benninga, N.; Bouman, G.P.; van Dijk, H.; Gaade, W.; Geldof, H.; Hackmann, J.Th.; Jonker, E.W.; Paap, T.; Zuiderweg, F.J., Study on the Preparation and the Physical Constants of A Number of Alkanes and Cycloalkanes, Recl. Trav. Chim. Pays-Bas, 1939, 58, 329. [all data]

Smittenberg, Hoog, et al., 1938
Smittenberg, J.; Hoog, H.; Henkes, R.A., Freezing Points of A Number of Pure Hydrocarbons of the Gasoline Boiling Range and of Some of their Binary Mixtures, J. Am. Chem. Soc., 1938, 60, 17. [all data]

Leslie and Heuer, 1937
Leslie, R.T.; Heuer, W.W., Study of the Crystal Behavior of Hydrocarbons, J. Res. Natl. Bur. Stand. (U. S.), 1937, 18, 639. [all data]

Timmermans, 1935
Timmermans, J., Researches in Stoichiometry. I. The Heat of Fusion of Organic Compounds., Bull. Soc. Chim. Belg., 1935, 44, 17-40. [all data]

Timmermans and Delcourt, 1934
Timmermans, J.; Delcourt, Y., Work of the International Bureau of Physico-Chemical Standards.VI. Physical Constants of Twenty Organic Compounds., J. Chim. Phys. Phys.-Chim. Biol., 1934, 31, 85-121. [all data]

Timmermans, 1934
Timmermans, J., Theory of Concentrated Solutions XII., Bull. Soc. Chim. Belg., 1934, 43, 626. [all data]

Mair, 1932
Mair, B.J., The Synthesis, Purification, and Certain Physical Constants of the Normal Hydrocarbons from Pentane to Dodecane, of n-Amyl Bromide and of n-Nonyl Bromide, J. Res. Natl. Bur. Stand. (U. S.), 1932, 9, 457. [all data]

Shepard, Henne, et al., 1931
Shepard, A.F.; Henne, A.L.; Midgley, T., Physical Prop. of the Normal Paraffin Hydrocarbons Pentane to Dodecane, J. Am. Chem. Soc., 1931, 53, 1948. [all data]

Bruun and Hicks-Brunn, 1930
Bruun, J.H.; Hicks-Brunn, M.M., The Isolation of the Isomers of Hexane from Petroleum, J. Res. Natl. Bur. Stand. (U. S.), 1930, 5, 933. [all data]

Timmermans and Martin, 1928
Timmermans, J.; Martin, F., Study of the Physical Constants of Twenty Organic Compounds of the Physical Constants of Twenty Organic Compounds, J. Chim. Phys. Phys.-Chim. Biol., 1928, 25, 411. [all data]

Lievens, 1924
Lievens, G., The freezing point of organic substances: viii esters containing a normal c(5) radical, Bull. Soc. Chim. Belg., 1924, 33, 122-131. [all data]

Timmermans, 1911
Timmermans, J., Researches on the freezing point of organic liquid compounds, Bull. Soc. Chim. Belg., 1911, 25, 300. [all data]

Notes

Go To: Top, Normal melting point, References

• Symbols used in this document:
  

  Tfus	Fusion (melting) point

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.