Butanedioic acid
- Formula: C4H6O4
- Molecular weight: 118.0880
- IUPAC Standard InChI: InChI=1S/C4H6O4/c5-3(6)1-2-4(7)8/h1-2H2,(H,5,6)(H,7,8)
- IUPAC Standard InChIKey: KDYFGRWQOYBRFD-UHFFFAOYSA-N
- CAS Registry Number: 110-15-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Succinic acid; Amber acid; Asuccin; Bernsteinsaure; Dihydrofumaric acid; Katasuccin; Wormwood acid; 1,2-Ethanedicarboxylic acid; Ethanedicarboxylic acid; Wormwood; Kyselina jantarova; Acid of amber; Ethylene succinic acid; Sal succini; Salt of amber; Succinellite; 1,4-Butanedioic acid; NSC 106449
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Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.)
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| ΔcH°solid (kJ/mol) | Method | Reference | Comment |
|---|---|---|---|
| -1492.5 ± 0.4 | Ccb | Vasil'ev, Borodin, et al., 1991 | Corresponding ΔfHºsolid = -939.0 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1491.2 ± 0.19 | Ccb | Vanderzee, Mansson, et al., 1972 | Corresponding ΔfHºsolid = -940.35 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1491.3 ± 0.2 | Ccb | Zaikin and Nazaruk, 1970 | Corresponding ΔfHºsolid = -940.19 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1490.9 ± 0.3 | Ccr | Bills and Cotton, 1964 | Reanalyzed by Cox and Pilcher, 1970, Original value = -1492.2 kJ/mol; Corresponding ΔfHºsolid = -940.61 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1495. ± 2. | Ccb | Miroshnichenko, Leiko, et al., 1964 | Corresponding ΔfHºsolid = -936.0 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1490.7 ± 0.4 | Ccb | Wilhoit and Shiao, 1964 | Corresponding ΔfHºsolid = -940.86 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1490.8 ± 0.3 | Ccr | Good, Douslin, et al., 1959 | Reanalyzed by Cox and Pilcher, 1970, Original value = -1492.1 kJ/mol; Corresponding ΔfHºsolid = -940.73 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1490.8 ± 0.63 | Ccr | Keith and Mackle, 1958 | Reanalyzed by Cox and Pilcher, 1970, Original value = -1492.1 kJ/mol; Corresponding ΔfHºsolid = -940.69 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1489.0 ± 0.3 | Ccb | Cass, Springall, et al., 1955 | Reanalyzed by Cox and Pilcher, 1970, Original value = -1492.1 ± 0.3 kJ/mol; Corresponding ΔfHºsolid = -942.49 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1491.2 ± 0.3 | Ccb | Pilcher and Sutton, 1955 | Reanalyzed by Cox and Pilcher, 1970, Original value = -1492.4 ± 0.3 kJ/mol; Corresponding ΔfHºsolid = -940.35 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1487. | Ccb | Skuratov, Strepikheev, et al., 1953 | Averaged value; Corresponding ΔfHºsolid = -944.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1492.8 ± 1.3 | Ccb | Breitenbach and Derkosch, 1951 | Corresponding ΔfHºsolid = -938.72 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1490.5 ± 0.4 | Ccb | Huffman, 1938 | Author's hf298_condensed=-225.66±0.06 kcal/mol; Corresponding ΔfHºsolid = -941.02 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1491.1 ± 4.1 | Ccb | Roth and Becker, 1937 | Reanalyzed by Cox and Pilcher, 1970, Original value = -1495. ± 1. kJ/mol; Corresponding ΔfHºsolid = -940.44 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1490.8 ± 0.50 | Ccb | Keffler, 1934 | Reanalyzed by Cox and Pilcher, 1970, Original value = -1494.3 ± 0.2 kJ/mol; Corresponding ΔfHºsolid = -940.77 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| -1491.5 ± 0.50 | Ccb | Verkade, Hartman, et al., 1926 | Reanalyzed by Cox and Pilcher, 1970, Original value = -1494. kJ/mol; See Verkade, Hartman, et al., 1924; Corresponding ΔfHºsolid = -940.06 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
References
Go To: Top, Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Vasil'ev, Borodin, et al., 1991
Vasil'ev, V.P.; Borodin, V.A.; Kopnyshev, S.B.,
Calculation of the standard enthalpies of combustion and of formation of crystalline organic acids and complexones from the energy contributions of atomic groups,
Russ. J. Phys. Chem. (Engl. Transl.), 1991, 65, 29-32. [all data]
Vanderzee, Mansson, et al., 1972
Vanderzee, C.E.; Mansson, M.; Sunner, S.,
The energy of combustion of succinic acid,
J. Chem. Thermodyn., 1972, 4, 533-540. [all data]
Zaikin and Nazaruk, 1970
Zaikin, I.D.; Nazaruk, L.N.,
Heat of combustion of succinic acid,
Russ. J. Phys. Chem. (Engl. Transl.), 1970, 44, 1376. [all data]
Bills and Cotton, 1964
Bills, J.L.; Cotton, F.A.,
The enthalpy of formation of tetraethylgermane and the germanium-carbon bond energy,
J. Phys. Chem., 1964, 68, 806-810. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Miroshnichenko, Leiko, et al., 1964
Miroshnichenko, E.A.; Leiko, V.P.; Lebedev, Yu.A.,
A semimicrocalorimeter,
Russ. J. Phys. Chem. (Engl. Transl.), 1964, 38, 1054-1055. [all data]
Wilhoit and Shiao, 1964
Wilhoit, R.C.; Shiao, D.,
Thermochemistry of biologically important compounds. Heats of combustion of solid organic acids.,
J. Chem. Eng. Data, 1964, 9, 595-599. [all data]
Good, Douslin, et al., 1959
Good, W.D.; Douslin, D.R.; Scott, D.W.; George, A.; Lacina, J.L.; Dawson, J.P.; Waddington, G.,
Thermochemistry and vapor pressure of aliphatic fluorocarbons. A comparison of the C-F and C-H thermochemical bond energies,
J. Phys. Chem., 1959, 63, 1133-1138. [all data]
Keith and Mackle, 1958
Keith, W.A.; Mackle, H.,
A fluidless direct-drive moving bomb calorimeter,
Trans. Faraday Soc., 1958, 54, 353-366. [all data]
Cass, Springall, et al., 1955
Cass, R.C.; Springall, H.D.; Quincey, P.G.,
Heats of combustion and molecular structure. Part III. Diphenylene,
J. Chem. Soc., 1955, 1188-1190. [all data]
Pilcher and Sutton, 1955
Pilcher, G.; Sutton, L.E.,
A new high precision calorimeter for the measurement of heats of combustion: and the heat of combustion of succinic acid,
Phil. Trans. Roy. Soc. London, 1955, 248, 23-44. [all data]
Skuratov, Strepikheev, et al., 1953
Skuratov, S.M.; Strepikheev, A.A.; Kachinskaya, O.N.; Shtekher, S.M.; Brykina, E.P.,
Heat of combustion of heterocyclic compounds. I. Methods,
Uch. Zap. Mosk. Gos. Univ. im. M. V. Lomonosova, 1953, 73-85. [all data]
Breitenbach and Derkosch, 1951
Breitenbach, J.W.; Derkosch, J.,
Verbrennungswarmen von peroxyden und verwandten verbindungen sowie von polystrolen,
Monatsh. Chem., 1951, 82, 177-179. [all data]
Huffman, 1938
Huffman, H.M.,
Thermal data. IX. The heats of combustion of hippuric and succinic acids and a proposal for the use of hippuric acid as a secondary standard in combustion calorimetry,
J. Am. Chem. Soc., 1938, 60, 1171-1177. [all data]
Roth and Becker, 1937
Roth, W.A.; Becker, G.,
Bernsteinsaure als sekundare eichsubstanz fur verbrennungsbombe,
Z. Phys. Chem., 1937, 179, 450-456. [all data]
Keffler, 1934
Keffler, L.J.P.,
Researches upon prospective standard substances for bomb calorimetry. VI A study of succinic acid,
J. Phys. Chem., 1934, 38, 717-733. [all data]
Verkade, Hartman, et al., 1926
Verkade, P.E.; Hartman, H.; Coops, J.,
Calorimetric researches. X. Heats of combustion of successive terms of homologous series: dicarboxylic acids of the oxalic acid series,
Rec. Trav. Chim. Pays/Bas, 1926, 45, 373-393. [all data]
Verkade, Hartman, et al., 1924
Verkade, P.E.; Hartman, H.; Coops, J., Jr.,
Chemistry - The molecular heat of combustion of successive terms of homologous series,
Kom. Med. Akad. Ueknschap. Proc., 1924, 27, 859-866. [all data]
Notes
Go To: Top, Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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