Butanediamide
- Formula: C4H8N2O2
- Molecular weight: 116.1185
- IUPAC Standard InChIKey: SNCZNSNPXMPCGN-UHFFFAOYSA-N
- CAS Registry Number: 110-14-5
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Succinamide; Succindiamide; Succinic acid diamide; Succinic amide
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -581.2 ± 2.1 | kJ/mol | Ccb | Tavernier and Lamouroux, 1957 | Reanalyzed by Cox and Pilcher, 1970, Original value = -577.074 kJ/mol; Author's hf298_condensed=-139.977 kcal/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -2136.1 ± 2.1 | kJ/mol | Ccb | Tavernier and Lamouroux, 1957 | Reanalyzed by Cox and Pilcher, 1970, Original value = -2140.30 kJ/mol; Author's hf298_condensed=-139.977 kcal/mol; ALS |
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
174.0 | 323. | Satoh and Sogabe, 1941 | T = 0 to 100°C. Mean value.; DH |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference |
---|---|---|---|
6.08 | 485.9 | DSC | Badea, Gatta, et al., 2006 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner)
Proton affinity at 298K
Proton affinity (kJ/mol) | Reference |
---|---|
942. | Witt and Grutzmacher, 2000 |
Protonation entropy at 298K
Protonation entropy (J/mol*K) | Reference |
---|---|
-19. | Witt and Grutzmacher, 2000 |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Tavernier and Lamouroux, 1957
Tavernier, P.; Lamouroux, M.,
Determinations calorimetriques relatives a vingt et une substances organiques,
Mem. Poudres, 1957, 39, 335-356. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Satoh and Sogabe, 1941
Satoh, S.; Sogabe, T.,
The heat capacities of some organic compounds containing nitrogen and the atomic heat of nitrogen. (4), Sci.,
Pap. Inst. Phys. Chem. Res. (Tokyo), 1941, 38, 246-251. [all data]
Badea, Gatta, et al., 2006
Badea, Elena; Gatta, Giuseppe Della; D'Angelo, Domenico; Brunetti, Bruno; Recková, Zuzana,
Odd--even effect in melting properties of 12 alkane-α,ω-diamides,
The Journal of Chemical Thermodynamics, 2006, 38, 12, 1546-1552, https://doi.org/10.1016/j.jct.2006.04.004
. [all data]
Witt and Grutzmacher, 2000
Witt, M.; Grutzmacher, H.F.,
Effects of internal hydrogen bonds between amide groups: Gas-phase basicity and proton affinity of linear aliphatic dicarboxamides,
European J. Mass Spectrom., 2000, 6, 97. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔfusH Enthalpy of fusion - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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