Ethene, ethoxy-
- Formula: C4H8O
- Molecular weight: 72.1057
- IUPAC Standard InChIKey: FJKIXWOMBXYWOQ-UHFFFAOYSA-N
- CAS Registry Number: 109-92-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Vinamar; Ether, ethyl vinyl; Ethoxyethene; Ethoxyethylene; Ethyl vinyl ether; EVE; Vinyl ethyl ether; 1-Ethoxyethene; CH2=CHOC2H5; Ethyl ethenyl ether; Ether, vinyl ethyl; 1-Ethoxyethylene; Ethyloxyethene; NSC 8405; ((Vinyl)oxy)ethane
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Condensed phase thermochemistry data
Go To: Top, Phase change data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -166.6 ± 1.6 | kJ/mol | Ccb | Pilcher, Skinner, et al., 1963 | Heat of formation derived by Cox and Pilcher, 1970 |
ΔfH°liquid | -167.9 ± 1.6 | kJ/mol | Chyd | Dolliver, Gresham, et al., 1938 | Heat of formation derived by Cox and Pilcher, 1970 |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -2540. ± 10. | kJ/mol | Ccb | Favorskii and Shostakovskii, 1943 | Corresponding ΔfHºliquid = -178. kJ/mol (simple calculation by NIST; no Washburn corrections) |
Phase change data
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 306.2 | K | N/A | Aldrich Chemical Company Inc., 1990 | BS |
Tboil | 306. | K | N/A | Farchan Laboratories, 1990 | BS |
Tboil | 308.7 | K | N/A | Weast and Grasselli, 1989 | BS |
Tboil | 308.65 | K | N/A | Owen and Sorensen, 1979 | Uncertainty assigned by TRC = 1.5 K; TRC |
Tboil | 308.87 | K | N/A | Dolliver, Gresham, et al., 1938, 2 | Uncertainty assigned by TRC = 0.15 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 157.35 | K | N/A | Dolliver, Gresham, et al., 1938, 2 | Uncertainty assigned by TRC = 0.3 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 475. | K | N/A | Kobe, Ravicz, et al., 1956 | Uncertainty assigned by TRC = 2. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 40.7479 | bar | N/A | Kobe, Ravicz, et al., 1956 | Uncertainty assigned by TRC = 0.6894 bar; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 26.4 | kJ/mol | N/A | Pilcher, Skinner, et al., 1963 | DRB |
ΔvapH° | 26.6 ± 1.3 | kJ/mol | E | Dolliver, Gresham, et al., 1938 | Heat of formation derived by Cox and Pilcher, 1970; ALS |
ΔvapH° | 26.6 | kJ/mol | N/A | Dolliver, Gresham, et al., 1938 | DRB |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
29.5 | 238. | A | Stephenson and Malanowski, 1987 | Based on data from 223. to 309. K.; AC |
IR Spectrum
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compiled by: Coblentz Society, Inc.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pilcher, Skinner, et al., 1963
Pilcher, G.; Skinner, H.A.; Pell, A.S.; Pope, A.E.,
Measurements of heats of combustion by flame calorimetry. Part 1.-Diethyl ether, ethyl vinyl ether and divinyl ether,
Trans. Faraday Soc., 1963, 59, 316-330. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Dolliver, Gresham, et al., 1938
Dolliver, M.A.; Gresham, T.L.; Kistiakowsky, G.B.; Smith, E.A.; Vaughan, W.E.,
Heats of organic reactions. VI. Heats of hydrogenation of some oxygen-containing compounds,
J. Am. Chem. Soc., 1938, 60, 440-450. [all data]
Favorskii and Shostakovskii, 1943
Favorskii, A.E.; Shostakovskii, M.F.,
Vinyl ethers. I. Synthesis and properties of vinyl ethers,
Zh. Obshch. Kim., 1943, 13, 1-20. [all data]
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]
Farchan Laboratories, 1990
Farchan Laboratories,
Research Chemicals Catalog, Farchan Laboratories, Gainesville, FL, 1990, 91. [all data]
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Owen and Sorensen, 1979
Owen, N.L.; Sorensen, G.O.,
Microwave spectrum, conformation, and barrier to internal rotation of ethyl vinyl ether,
J. Phys. Chem., 1979, 83, 1483. [all data]
Dolliver, Gresham, et al., 1938, 2
Dolliver, M.A.; Gresham, T.L.; Kistiakowsky, G.B.; Smith, E.A.; Vaughan, W.E.,
Heats of Organic Reactions VI. Heats of Hydrogenation of Some Oxygen- Containing Compounds,
J. Am. Chem. Soc., 1938, 60, 440. [all data]
Kobe, Ravicz, et al., 1956
Kobe, K.A.; Ravicz, A.E.; Vohra, S.P.,
Critical Properties and Vapor Pressures of Some Ethers and Heterocyclic Compounds,
J. Chem. Eng. Data, 1956, 1, 50. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, References
- Symbols used in this document:
Pc Critical pressure Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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