1,3,5-Triazine-2,4,6-triamine

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub120. ± 4.kJ/molVHirt, Steger, et al., 1960ALS

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
123.3432.AStephenson and Malanowski, 1987Based on data from 417. to 447. K.; AC
121.3 ± 4.2515.GSHirt, Steger, et al., 1960Based on data from 417. to 614. K. See also Cox and Pilcher, 1970.; AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

6Urea = 1,3,5-Triazine-2,4,6-triamine + 3Carbon dioxide + 6Ammonia

By formula: 6CH4N2O = C3H6N6 + 3CO2 + 6H3N

Quantity Value Units Method Reference Comment
Δr469.4kJ/molEqkRukevich and Zagranichnyi, 1971liquid phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hirt, Steger, et al., 1960
Hirt, R.C.; Steger, J.E.; Simard, G.L., Vapor pressure of 2,4,6-triamino-s-triazine (melamine), J. Polym. Sci., 1960, 43, 319-323. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]

Rukevich and Zagranichnyi, 1971
Rukevich, O.S.; Zagranichnyi, V.I., Equilibrium in the reaction of melamine formation from urea, J. Anal. Chem. USSR, 1971, 44, 1616-1620. [all data]


Notes

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