Benzene, 1,1'-(1,6-hexanediyl)bis-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δcliquid-10230.kJ/molCcbSerijan and Wise, 1951Corresponding Δfliquid = 8. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil618.82KN/ASerijan and Wise, 1951, 2Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tfus261.16KN/ASerijan and Wise, 1951, 2Uncertainty assigned by TRC = 0.05 K; TRC
Tfus280.1KN/ABoelhouwer, Nederbragt, et al., 1950Uncertainty assigned by TRC = 2. K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
88.0308.AStephenson and Malanowski, 1987Based on data from 293. to 373. K. See also Morecroft, 1964.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
293. to 373.8.501394715.8734.488Morecroft, 1964Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated by: Edward P. Hunter and Sharon G. Lias

Quantity Value Units Method Reference Comment
Proton affinity (review)826.1kJ/molN/AHunter and Lias, 1998 
Quantity Value Units Method Reference Comment
Gas basicity783.8kJ/molN/AHunter and Lias, 1998 

Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Div. of Experiment Therapeutics WRAIR, WRAMC, Washington DC 20307
NIST MS number 212230

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References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Serijan and Wise, 1951
Serijan, K.T.; Wise, P.H., Dicyclic hydrocarbons. IV. Synthesis and physical properties of α,α- and α,omega-diphenyl- and dicyclohexyl- pentanes and hexanes, J. Am. Chem. Soc., 1951, 73, 5191-5193. [all data]

Serijan and Wise, 1951, 2
Serijan, K.T.; Wise, P.H., Dicyclic hydrocarboms. IV. Synthesis and Physical properties of alpha,alpha - and alpha,omega-diphenyl- and dicyclohexyl- pentanes and hexanes, J. Am. Chem. Soc., 1951, 73, 5191. [all data]

Boelhouwer, Nederbragt, et al., 1950
Boelhouwer, J.W.M.; Nederbragt, G.W.; Verberg, G.W., Viscosity data of organic liquids, Appl. Sci. Res., Sect. A, 1950, 2, 249. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Morecroft, 1964
Morecroft, D.W., Vapor Pressures of Some High Molecular Weight Hydrocarbons., J. Chem. Eng. Data, 1964, 9, 4, 488-490, https://doi.org/10.1021/je60023a003 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References