Propylene Carbonate
- Formula: C4H6O3
- Molecular weight: 102.0886
- IUPAC Standard InChIKey: RUOJZAUFBMNUDX-UHFFFAOYSA-N
- CAS Registry Number: 108-32-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Stereoisomers:
- Other names: 1,3-Dioxolan-2-one, 4-methyl-; Carbonic acid, cyclic propylene ester; Cyclic methylethylene carbonate; Cyclic propylene carbonate; Cyclic 1,2-propylene carbonate; Propylene glycol cyclic carbonate; 1-Methylethylene carbonate; 1,2-Propanediol carbonate; 1,2-Propanediol cyclic carbonate; 1,2-Propanediyl carbonate; 1,2-Propylene carbonate; 4-Methyl-1,3-dioxolan-2-one; 1,2-Propylene glycol carbonate; 4-Methyl-1,3-dioxol-2-one; Dipropylene carbonate; 4-Methyldioxalone-2; 4-Methyl-2-oxo-1,3-dioxolane; 1,2-PDC; Propylenester kyseliny uhlicite; Arconate propylene carbonate; PC-HP; Solvenon PC; Texacar PC; Arconate 5000; Carbonic acid cyclic methylethylene ester; Carbonic acid, propylene ester; NSC 11784
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Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
| ΔvapH° (kJ/mol) | Method | Reference | Comment |
|---|---|---|---|
| 61.5 ± 0.3 | GS | Verevkin, Toktonov, et al., 2008 | Based on data from 298. to 345. K.; AC |
| 71.3 | N/A | Nasirzadeh, Neueder, et al., 2005 | Based on data from 294. to 473. K.; AC |
| 61.3 ± 0.1 | E | Chernyak and Clements, 2004 | Based on data from 460. to 513. K. See also Verevkin, Toktonov, et al., 2008.; AC |
| 71.2 ± 0.6 | N/A | Wilson, VonNiederhausern, et al., 2002 | Based on data from 668. to 762. K. See also Verevkin, Toktonov, et al., 2008.; AC |
| 30.7 ± 2.1 | V | Choi and Joncich, 1971 | Pedley's value is off by 4.46kcal/mol; ALS |
| 49.3 | N/A | Choi and Joncich, 1971 | DRB |
References
Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Verevkin, Toktonov, et al., 2008
Verevkin, Sergey P.; Toktonov, Alexey V.; Chernyak, Yury; Schäffner, Benjamin; Börner, Armin,
Vapour pressure and enthalpy of vaporization of cyclic alkylene carbonates,
Fluid Phase Equilibria, 2008, 268, 1-2, 1-6, https://doi.org/10.1016/j.fluid.2008.03.013
. [all data]
Nasirzadeh, Neueder, et al., 2005
Nasirzadeh, Karamat; Neueder, Roland; Kunz, Werner,
Vapor Pressures of Propylene Carbonate and N , N -Dimethylacetamide,
J. Chem. Eng. Data, 2005, 50, 1, 26-28, https://doi.org/10.1021/je049950g
. [all data]
Chernyak and Clements, 2004
Chernyak, Yury; Clements, John H.,
Vapor Pressure and Liquid Heat Capacity of Alkylene Carbonates,
J. Chem. Eng. Data, 2004, 49, 5, 1180-1184, https://doi.org/10.1021/je034173q
. [all data]
Wilson, VonNiederhausern, et al., 2002
Wilson, Grant M.; VonNiederhausern, David M.; Giles, Neil F.,
Critical Point and Vapor Pressure Measurements for Nine Compounds by a Low Residence Time Flow Method,
J. Chem. Eng. Data, 2002, 47, 4, 761-764, https://doi.org/10.1021/je0100995
. [all data]
Choi and Joncich, 1971
Choi, J.K.; Joncich, M.J.,
Heats of combustion, heats of formation and vapor pressures of some organic carbonates. Estimation of carbonate group contribution to heat of formation,
J. Chem. Eng. Data, 1971, 16, 87-90. [all data]
Notes
Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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