L-Glutamic acid, 3TBDMS derivative

• Formula: C₂₃H₅₁NO₄Si₃
• Molecular weight: 489.9118
• IUPAC Standard InChI: InChI=1S/C23H51NO4Si3/c1-21(2,3)29(10,11)24-18(20(26)28-31(14,15)23(7,8)9)16-17-19(25)27-30(12,13)22(4,5)6/h18,24H,16-17H2,1-15H3/t18-/m1/s1 Copy

  
• IUPAC Standard InChIKey: WBLAMWCQIMLWPE-GOSISDBHSA-N Copy
• CAS Registry Number: 107715-97-9
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: L-Glutamic acid, N-(tert-butyldimethylsilyl)-, bis(tert-butyldimethylsilyl) ester; Bis[tert-butyl(dimethyl)silyl] 2-([tert-butyl(dimethyl)silyl]amino)pentanedioate, (L)-; Glutamic acid, triTBDMS; Glu, tris-TBDMS; Glu, TBDMS
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• Information on this page:
  • Mass spectrum (electron ionization)
  • Gas Chromatography
  • References
  • Notes
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Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Normal alkane RI, non-polar column, temperature ramp

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ohie, Fu, et al., 2000
Ohie, T.; Fu, X.; Iga, M.; Kimura, M.; Yamaguchi, S., Gas chromatography-mass spectrometry with tert .-butyldimethylsilyl derivatization: use of the simplified sample preparations and the automated data system to screen for organic acidemias, J. Chromatogr. B, 2000, 746, 1, 63-73, https://doi.org/10.1016/S0378-4347(00)00105-5 . [all data]

Tret'yakov, 2007
Tret'yakov, K.V., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]

Tsunoda, 1993
Tsunoda, N., Simultaneous determination of the herbicides glyphosate, glufosinate and bialaphos and their metabolites by capillary gas chromatography-ion-trap mass spectrometry, J. Chromatogr., 1993, 637, 2, 167-173, https://doi.org/10.1016/0021-9673(93)83209-B . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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