L-Valine, 2TBDMS derivative

• Formula: C₁₇H₃₉NO₂Si₂
• Molecular weight: 345.6681
• IUPAC Standard InChI: InChI=1S/C17H39NO2Si2/c1-13(2)14(18-21(9,10)16(3,4)5)15(19)20-22(11,12)17(6,7)8/h13-14,18H,1-12H3/t14-/m1/s1 Copy

  
• IUPAC Standard InChIKey: KPMGOLUDVQVDCW-CQSZACIVSA-N Copy
• CAS Registry Number: 107715-89-9
• Chemical structure:
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• Other names: L-Valine, N-(tert-butyldimethylsilyl)-, tert-butyldimethylsilyl ester; N,O-Bis(dimethyl-t-butylsilyl)-l-valine; tert-Butyl(dimethyl)silyl 2-([tert-butyl(dimethyl)silyl]amino)-3-methylbutanoate, (L)-; Valine diTBDMS; Valine, bis-TBDMS; Val, bis-TBDMS; Val, TBDMS; Valine, TBDMS
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• Information on this page:
  • Mass spectrum (electron ionization)
  • Gas Chromatography
  • References
  • Notes
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Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Normal alkane RI, non-polar column, temperature ramp

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ohie, Fu, et al., 2000
Ohie, T.; Fu, X.; Iga, M.; Kimura, M.; Yamaguchi, S., Gas chromatography-mass spectrometry with tert .-butyldimethylsilyl derivatization: use of the simplified sample preparations and the automated data system to screen for organic acidemias, J. Chromatogr. B, 2000, 746, 1, 63-73, https://doi.org/10.1016/S0378-4347(00)00105-5 . [all data]

Tret'yakov, 2007
Tret'yakov, K.V., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]

Tsunoda, 1993
Tsunoda, N., Simultaneous determination of the herbicides glyphosate, glufosinate and bialaphos and their metabolites by capillary gas chromatography-ion-trap mass spectrometry, J. Chromatogr., 1993, 637, 2, 167-173, https://doi.org/10.1016/0021-9673(93)83209-B . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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