Sarin
- Formula: C4H10FO2P
- Molecular weight: 140.0932
- IUPAC Standard InChI: InChI=1S/C4H10FO2P/c1-4(2)7-8(3,5)6/h4H,1-3H3
- IUPAC Standard InChIKey: DYAHQFWOVKZOOW-UHFFFAOYSA-N
- CAS Registry Number: 107-44-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: O-Isopropyl methylphosphonofluoridate; Phosphonofluoridic acid, methyl-, 1-methylethyl ester; Phosphonofluoridic acid, methyl-, isopropyl ester; GB; Isopropoxymethylphosphoryl fluoride; Isopropyl methylfluorophosphonate; Isopropyl methylphosphonofluoridate; Methylfluorophosphoric acid isopropyl ester; Methylphosphonofluoridic acid isopropyl ester; O-Isopropyl methylfluorophosphonate; Zarin; EA 1208; IMPF; Isopropylester kyseliny methylfluorfosfonove; Isopropyl methanefluorophosphonate; Isopropyl methylfluorophosphate; Isopropyl-methyl-phosphoryl fluoride; Methylfluorphosphorsaeureisopropyl ester; Methylphosphonofluoridic acid 1-methylethyl ester; MFI; Phosphine oxide, fluoroisopropoxymethyl-; Phosphoric acid, methylfluoro-, isopropyl ester; Sarin II; T-144; T-2106; TL 1618; Trilone 46; 1-Methylethyl methylphosphonofluoridate; Phosphonofluoridic acid, P-methyl-, 1-methylethyl ester; (.+/-.)-Sarin
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Gas Chromatography
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 792. | Kostiainen, 2000 | 15. m/0.32 mm/0.25 μm, He, 50. C @ 2. min, 10. K/min, 280. C @ 10. min |
| Capillary | SE-54 | 820. | Kostiainen, 2000 | 25. m/0.32 mm/0.25 μm, He, 40. C @ 1. min, 10. K/min, 280. C @ 10. min |
| Capillary | SE-54 | 818.37 | Kaipainen, Kostiainen, et al., 1992 | 25. m/0.32 mm/0.25 μm, He, 40. C @ 1. min, 10. K/min; Tend: 280. C |
| Capillary | SE-54 | 819.25 | Kaipainen, Kostiainen, et al., 1992 | 25. m/0.32 mm/0.25 μm, He, 40. C @ 1. min, 10. K/min; Tend: 280. C |
| Capillary | DB-1 | 789. | Hancock and Peters, 1991 | He, 50. C @ 2. min, 10. K/min; Column length: 15. m; Column diameter: 0.53 mm |
| Capillary | DB-5 | 817. | Hancock and Peters, 1991 | He, 50. C @ 2. min, 10. K/min; Column length: 15. m; Column diameter: 0.53 mm |
| Capillary | DB-1 | 791.8 | D'Agostino and Provost, 1985 | 15. m/0.32 mm/0.25 μm, He, 50. C @ 2. min, 10. K/min, 300. C @ 5. min |
| Capillary | DB-5 | 823.8 | D'Agostino and Provost, 1985 | 15. m/0.32 mm/0.25 μm, He, 50. C @ 2. min, 10. K/min; Tend: 300. C |
Van Den Dool and Kratz RI, polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-Wax | 1278.4 | D'Agostino and Provost, 1985 | 15. m/0.32 mm/0.25 μm, He, 50. C @ 2. min, 10. K/min, 250. C @ 5. min |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-54 | 820.2 | Söderström, Ketola, et al., 1995 | 25. m/0.32 mm/0.25 μm, He, 40. C @ 2. min, 10. K/min, 250. C @ 10. min |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Polydimethyl siloxane | 820. | Staples, 2006 | Program: not specified |
| Capillary | DB-1 | 789. | Tsunoda, 2005 | Program: not specified |
| Capillary | DB-5 MS | 817. | Tsunoda, 2005 | 30. m/0.25 mm/0.25 μm, Helium; Program: 45 0C (2 min) 8 0C/min -> 125 0C 15 0C/min -> 280 0C |
| Capillary | SE-54 | 824. | Tsunoda, 2005 | Program: not specified |
| Capillary | 5 % Phenyl methyl siloxane | 820. | OPCW, 1997 | Program: not specified |
Normal alkane RI, polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-Wax | 1297. | Tsunoda, 2005 | Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kostiainen, 2000
Kostiainen, O.,
Gas Chromatography in Screening of Chemicals Related to the Chemical Weapons Convention
in Encyclopedia of Analytical Chemistry, Meyers, R.A., ed(s)., John Wiley Sons Ltd, Chichester, 2000, 963-979. [all data]
Kaipainen, Kostiainen, et al., 1992
Kaipainen, A.; Kostiainen, O.; Riekkola, M.-L.,
Identification of chemical warfare agents in air samples using capillary column gas chromatography with three simultaneous detectors,
J. Microcolumn Sep., 1992, 4, 3, 245-251, https://doi.org/10.1002/mcs.1220040311
. [all data]
Hancock and Peters, 1991
Hancock, J.R.; Peters, G.R.,
Retention index monitoring of compounds of chemical defence interest using thermal desorption gas chromatography,
J. Chromatogr., 1991, 538, 2, 249-257, https://doi.org/10.1016/S0021-9673(01)88845-2
. [all data]
D'Agostino and Provost, 1985
D'Agostino, P.A.; Provost, L.R.,
Gas chromatographic retention indices of chemical warfare agents and simulants,
J. Chromatogr., 1985, 331, 47-54, https://doi.org/10.1016/0021-9673(85)80005-4
. [all data]
Söderström, Ketola, et al., 1995
Söderström, M.T.; Ketola, R.A.; Kostiainen, O.,
Identification of some nerve agent homologues and dialkyl methylphosphonates by gas chromatography/Fourier transform infrared spectrometry. Part II. Spectral search with the help of retention indices,
Fresenius J. Anal. Chem., 1995, 352, 6, 550-556, https://doi.org/10.1007/BF00323072
. [all data]
Staples, 2006
Staples, E.J.,
Creating a compound library for chemical warfare agents for the ZNose, 2006, retrieved from http://www.estcal.com/TechPapers/Security/CWA-Libraries.pdf. [all data]
Tsunoda, 2005
Tsunoda, N.,
The sarin incidents in Japan and mass spectrometry,
J. MAss Spectrom. Soc. Japan, 2005, 53, 3, 157-163, https://doi.org/10.5702/massspec.53.157
. [all data]
OPCW, 1997
OPCW,
Conference of the States Parties C-I/DEC.64 (22 May 1997), 1997, retrieved from http://www.opcw.org/html/global/cseries/csp1/CIDEC64.html. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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