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Ethene, methoxy-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H5O- + Hydrogen cation = Ethene, methoxy-

By formula: C3H5O- + H+ = C3H6O

Quantity Value Units Method Reference Comment
Deltar1720. ± 50.kJ/molCIDTGraul and Squires, 1990gas phase; B
Quantity Value Units Method Reference Comment
Deltar1690. ± 50.kJ/molH-TSGraul and Squires, 1990gas phase; B

C3H7ClO = Ethene, methoxy- + Hydrogen chloride

By formula: C3H7ClO = C3H6O + HCl

Quantity Value Units Method Reference Comment
Deltar71.1kJ/molEqkCruickshank and Benson, 1969gas phase; ALS

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Graul and Squires, 1990
Graul, S.T.; Squires, R.R., Gas-Phase Acidities Derived from Threshold Energies for Activated Reactions, J. Am. Chem. Soc., 1990, 112, 7, 2517, https://doi.org/10.1021/ja00163a007 . [all data]

Cruickshank and Benson, 1969
Cruickshank, F.R.; Benson, S.W., Some thermochemical properties of methyl vinyl ether, «alpha»-chloroethyl methyl ether, and iodomethyl methyl ether. Evidence for nonbonded electrostatic interactions, J. Am. Chem. Soc., 1969, 91, 2487-2490. [all data]


Notes

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