Ethene, methoxy-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Glushko Thermocenter, Russian Academy of Sciences, Moscow

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
79.50298.15Cruickshank F.R., 1969 
79.91300.
99.16400.
115.90500.
130.12600.
151.04800.
166.941000.
190.791500.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H5O- + Hydrogen cation = Ethene, methoxy-

By formula: C3H5O- + H+ = C3H6O

Quantity Value Units Method Reference Comment
Δr1720. ± 50.kJ/molCIDTGraul and Squires, 1990gas phase; B
Quantity Value Units Method Reference Comment
Δr1690. ± 50.kJ/molH-TSGraul and Squires, 1990gas phase; B

C3H7ClO = Ethene, methoxy- + Hydrogen chloride

By formula: C3H7ClO = C3H6O + HCl

Quantity Value Units Method Reference Comment
Δr71.1kJ/molEqkCruickshank and Benson, 1969gas phase; ALS

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryMethyl Silicone416.Zenkevich, 1999Program: not specified
CapillaryPolydimethyl siloxanes416.Zenkevich, 1997Program: not specified

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cruickshank F.R., 1969
Cruickshank F.R., Thermodynamic properties of methyl vinyl ether, alpha-chloroethyl methyl ether, and iodomethyl methyl ether. Evidence for nonbonded electrostatic interactions, J. Am. Chem. Soc., 1969, 91, 2487-2492. [all data]

Graul and Squires, 1990
Graul, S.T.; Squires, R.R., Gas-Phase Acidities Derived from Threshold Energies for Activated Reactions, J. Am. Chem. Soc., 1990, 112, 7, 2517, https://doi.org/10.1021/ja00163a007 . [all data]

Cruickshank and Benson, 1969
Cruickshank, F.R.; Benson, S.W., Some thermochemical properties of methyl vinyl ether, α-chloroethyl methyl ether, and iodomethyl methyl ether. Evidence for nonbonded electrostatic interactions, J. Am. Chem. Soc., 1969, 91, 2487-2490. [all data]

Zenkevich, 1999
Zenkevich, I.G., New Application of the Retention Index Concept in Gas and High Performance Liquid Chromatography, Fresenius' J. Anal. Chem., 1999, 365, 4, 305-309, https://doi.org/10.1007/s002160051491 . [all data]

Zenkevich, 1997
Zenkevich, I.G., Influence of the Variations of Dynamics Molecular Parameterts on the Additivity of Chromatigraphic Retention Indices of Products of Organic Reactions Relative to Initial Reagents, Dokl. Akad. Nauk (Rus.), 1997, 353, 5, 625-627. [all data]


Notes

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