Diisopropyl mercury


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

C6H14Hg (l) + Cl2Hg (cr) = 2C3H7ClHg (cr)

By formula: C6H14Hg (l) + Cl2Hg (cr) = 2C3H7ClHg (cr)

Quantity Value Units Method Reference Comment
Δr-22.5 ± 0.50kcal/molRSCMortimer, Pritchard, et al., 1952Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

C6H14Hg (l) + Mercury(II) bromide (cr) = 2C3H7BrHg (cr)

By formula: C6H14Hg (l) + Br2Hg (cr) = 2C3H7BrHg (cr)

Quantity Value Units Method Reference Comment
Δr-21.2 ± 0.36kcal/molRSCMortimer, Pritchard, et al., 1952Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

C6H14Hg (l) + Mercury diiodide (cr) = 2C3H7HgI (cr)

By formula: C6H14Hg (l) + HgI2 (cr) = 2C3H7HgI (cr)

Quantity Value Units Method Reference Comment
Δr-15.6 ± 0.41kcal/molRSCMortimer, Pritchard, et al., 1952Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

2Propane, 2-iodo- + Mercury diiodide = C6H14Hg + 2Iodine

By formula: 2C3H7I + HgI2 = C6H14Hg + 2I2

Quantity Value Units Method Reference Comment
Δr57.92 ± 0.46kcal/molCmMortimer, Pritchard, et al., 1952, 2liquid phase; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mortimer, Pritchard, et al., 1952
Mortimer, C.T.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. Part V.?Mercury di-propyl and mercury di-isopropyl, Trans. Faraday Soc., 1952, 48, 220, https://doi.org/10.1039/tf9524800220 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Mortimer, Pritchard, et al., 1952, 2
Mortimer, C.T.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. Part V - Mercury di-propyl and mercury di-isopropyl, Trans. Faraday Soc., 1952, 48, 220-229. [all data]


Notes

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