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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
liquid229.06J/mol*KN/ATakeda, Yamamuro, et al., 1991 
liquid227.0J/mol*KN/AChao, Hall, et al., 1983 
liquid213.84J/mol*KN/AAston, Fink, et al., 1946 

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
128.96298.15Takeda, Yamamuro, et al., 1991T = 5 to 300 K.
118.298.15Chao, Hall, et al., 1983T = 12 to 360 K.
128.6294.Schlinger and Sage, 1949T = 294 to 378 K. Cp given as 0.548 Btu/lb*R at 70°F at bubble point.
119.45260.Aston, Fink, et al., 1946T = 11.5 to 260 K.
119.16253.4Todd and Parks, 1936T = 81 to 253 K. Value is unsmoothed experimental datum.


Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Takeda, Yamamuro, et al., 1991
Takeda, K.; Yamamuro, O.; Suga, H., Thermodynamic study of 1-butene. Exothermic and endothermic enthalpy relaxations near the glass transition, J. Phys. Chem. Solids, 1991, 22, 607-615. [all data]

Chao, Hall, et al., 1983
Chao, J.; Hall, K.R.; Yao, J.M., Thermodynamic properties of simple alkenes, Thermochim. Acta, 1983, 64(3), 285-303. [all data]

Aston, Fink, et al., 1946
Aston, J.G.; Fink, H.L.; Bestul, A.B.; Pace, E.L.; Szasz, G.J., The heat capacity and entropy, heats of fusion and vaporization and the vapor pressure of butene-1. The zero point entropy of the glass. The entropy of the gas from molecular data, J. Am. Chem. Soc., 1946, 68, 52-57. [all data]

Schlinger and Sage, 1949
Schlinger, W.G.; Sage, B.H., Isobaric heat capacity of 1-butene and 1-pentene at bubble point, Ind. Eng. Chem., 1949, 41, 1779-1782. [all data]

Todd and Parks, 1936
Todd, S.S.; Parks, G.S., Thermal data on organic compounds. XV. Some heat capacity, entropy and free energy data for the isomeric butenes, J. Am. Chem. Soc., 1936, 58, 134-137. [all data]


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