Butane
- Formula: C4H10
- Molecular weight: 58.1222
- IUPAC Standard InChIKey: IJDNQMDRQITEOD-UHFFFAOYSA-N
- CAS Registry Number: 106-97-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: n-Butane; Diethyl; Freon 600; Liquefied petroleum gas; LPG; n-C4H10; Butanen; Butani; Methylethylmethane; UN 1011; A 21; HC 600; HC 600 (hydrocarbon); R 600; R 600 (alkane)
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Critical pressure
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
Pc (atm) | Reference | Comment |
---|---|---|
37.46 ± 0.1 | Ambrose and Tsonopoulos, 1995 | |
37.47 | Teja, Lee, et al., 1989 | TRC |
37.43 | Brunner, 1988 | Uncertainty assigned by TRC = 0.05 atm; Visual, optical cell 30cm high. P transducer cal. vs PB.; TRC |
37.50 | Li and Kiran, 1988 | Uncertainty assigned by TRC = 0.59 atm; TRC |
37.46 | Younglove and Ely, 1987 | Uncertainty assigned by TRC = 0.02 atm; TRC |
37.46 | Haynes and Goodwin, 1982 | TRC |
37.3437 | Kratzke, Spillner, et al., 1982 | Uncertainty assigned by TRC = 0.0015 atm; calculated from vapor pressure at Tc = 425.14 K, selected; TRC |
37.47 | Das, Reed, et al., 1973 | Uncertainty assigned by TRC = 0.09998 atm; TRC |
37.4796 | Kreglewski and Kay, 1969 | Uncertainty assigned by TRC = 0.2381 atm; TRC |
37.50 | Kay, 1964 | Uncertainty assigned by TRC = 0.5000 atm; TRC |
37.35 | Connolly, 1962 | Uncertainty assigned by TRC = 0.2000 atm; TRC |
37.4319 | Kay, 1941 | Uncertainty assigned by TRC = 0.0680 atm; TRC |
37.43 | Kay, 1940 | Uncertainty assigned by TRC = 0.0680 atm; TRC |
37.4700 | Beattie, Simard, et al., 1939 | Uncertainty assigned by TRC = 0.0400 atm; TRC |
35.6749 | Seibert and Burrell, 1915 | Uncertainty assigned by TRC = 0.2631 atm; TRC; Data excluded from overall average |
37.50 | Kuenen, 1911 | Uncertainty assigned by TRC = 1.0000 atm; TRC |
References
Go To: Top, Critical pressure, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ambrose and Tsonopoulos, 1995
Ambrose, D.; Tsonopoulos, C.,
Vapor-Liquid Critical Properties of Elements and Compounds. 2. Normal Alkenes,
J. Chem. Eng. Data, 1995, 40, 531-546. [all data]
Teja, Lee, et al., 1989
Teja, A.S.; Lee, R.J.; Rosenthal, D.J.; Anselme, M.J.,
Correlation of the Critical Properties of Alkanes and Alkanols
in 5th IUPAC Conference on Alkanes and AlkanolsGradisca, 1989. [all data]
Brunner, 1988
Brunner, E.,
Fluid Mixtures at High Pressures VI. Phase Separation and Critical Phenomena in 18 (n-Alkane + Ammonia) and 4 (n-Alkane _ Methanol) Mixtures,
J. Chem. Thermodyn., 1988, 20, 273. [all data]
Li and Kiran, 1988
Li, L.; Kiran, E.,
Gas-Liquid Critical Properties of Methylamine + Nitrous Oxide and Methylamine + Ethylene Binary Mixtures,
J. Chem. Eng. Data, 1988, 33, 342. [all data]
Younglove and Ely, 1987
Younglove, B.A.; Ely, J.F.,
Thermophysical Properties of Fluids II. Methane, Ethane, Propane, Isobutane, and Normal Butane,
J. Phys. Chem. Ref. Data, 1987, 16, 577. [all data]
Haynes and Goodwin, 1982
Haynes, W.M.; Goodwin, R.D.,
Thermopnhysical properties of normal butane from 135 to 700K at pressures to 70 MPa,
NBS Monogr. (U. S.), 1982, 1982, 197 pp.. [all data]
Kratzke, Spillner, et al., 1982
Kratzke, H.; Spillner, E.; Muller, S.,
Thermodynamic properties for n-butane--1. The vapour pressure of liquid n-butane,
J. Chem. Thermodyn., 1982, 14, 1175-81. [all data]
Das, Reed, et al., 1973
Das, T.R.; Reed, C.O.; Eubank, P.T.,
Pvt surface and thermodynamic properties of n-butane,
J. Chem. Eng. Data, 1973, 18, 244. [all data]
Kreglewski and Kay, 1969
Kreglewski, A.; Kay, W.B.,
The Critical Constants of Conformal Mixtures,
J. Phys. Chem., 1969, 73, 3359. [all data]
Kay, 1964
Kay, W.B.,
P-T-x Diagrams in the Critical Region. Acetone-n-Alkane Systems,
J. Phys. Chem., 1964, 68, 827-31. [all data]
Connolly, 1962
Connolly, J.F.,
Ideality of n-Butane:Isobutane Solutions,
J. Phys. Chem., 1962, 66, 1082. [all data]
Kay, 1941
Kay, W.B.,
Liquid-Vapor Equil. Relations in Binary Systems. Butane-Heptane Syst. System,
Ind. Eng. Chem., 1941, 33, 590-4. [all data]
Kay, 1940
Kay, W.B.,
Liquid-Vapor Equilibrium Relations in Binary Systems. The Ethane- Butane System,
Ind. Eng. Chem., 1940, 32, 353-7. [all data]
Beattie, Simard, et al., 1939
Beattie, J.A.; Simard, G.L.; Su, G.-J.,
The Vapor Pressure of Critical Constants of Normal Butane,
J. Am. Chem. Soc., 1939, 61, 24. [all data]
Seibert and Burrell, 1915
Seibert, F.M.; Burrell, G.A.,
The Critical Constants of Normal Butane, Iso-butane and Propylene and Their Vapor Pressures at Temperatures Bewtween 0 deg.C and 120 deg.C,
J. Am. Chem. Soc., 1915, 37, 2683-91. [all data]
Kuenen, 1911
Kuenen, J.P.,
Commun. Kamerlingh Onnes Lab. Univ. Leiden, 1911, No. 125, 1. [all data]
Notes
Go To: Top, Critical pressure, References
- Symbols used in this document:
Pc Critical pressure - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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