bromotrimethylstannane
- Formula: C3H9BrSn
- Molecular weight: 243.718
- CAS Registry Number: 1066-44-0
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -138.2 ± 5.6 | kJ/mol | Review | Martinho Simões | The enthalpy of formation relies on -49.7 ± 2.0 kJ/mol for the enthalpy of formation of Sn(Me)4(l). |
| ΔfH°gas | -145.6 | kJ/mol | Review | Martinho Simões | The enthalpy of formation relies on -379.8 ± 4.1 kJ/mol for the enthalpy of formation of Sn(Me)3(OH)(cr). |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -185.5 ± 3.7 | kJ/mol | Review | Martinho Simões | The enthalpy of formation relies on -49.7 ± 2.0 kJ/mol for the enthalpy of formation of Sn(Me)4(l). |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔfH°solid | -204.2 ± 4.1 | kJ/mol | Review | Martinho Simões | The enthalpy of formation relies on -379.8 ± 4.1 kJ/mol for the enthalpy of formation of Sn(Me)3(OH)(cr). |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 47.3 ± 4.2 | kJ/mol | RSC | Davies, Pope, et al., 1963 | |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔsubH° | 58.6 | kJ/mol | RSC | Baldwin, Lappert, et al., 1972 |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A.,
Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin,
Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233
. [all data]
Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S.,
J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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