Silanol, trimethyl-

• Formula: C₃H₁₀OSi
• Molecular weight: 90.1964
• IUPAC Standard InChI: InChI=1S/C3H10OSi/c1-5(2,3)4/h4H,1-3H3 Copy

  
• IUPAC Standard InChIKey: AAPLIUHOKVUFCC-UHFFFAOYSA-N Copy
• CAS Registry Number: 1066-40-6
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Hydroxytrimethylsilane; Trimethylhydroxysilane; Trimethylsilanol
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• Information on this page:
  • Reaction thermochemistry data
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C₃H₉OSi^- +  =

By formula: C₃H₉OSi^- + H⁺ = C₃H₁₀OSi

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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Normal alkane RI, non-polar column, custom temperature program

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Angelini, Johnson, et al., 1991
Angelini, G.; Johnson, C.E.; Brauman, J.I., Addition and Deprotonation in Reactions of Hydroxide Ion with a beta-Hydroxysilane, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 1, https://doi.org/10.1016/0168-1176(91)85093-2 . [all data]

Damrauer, Simon, et al., 1991
Damrauer, R.; Simon, R.; Krempp, M., Effect of Substituents on the Gas-Phase Acidity of Silanols, J. Am. Chem. Soc., 1991, 113, 12, 4431, https://doi.org/10.1021/ja00012a009 . [all data]

Zenkevich, 2005
Zenkevich, I.G., Experimentally measured retention indices., 2005. [all data]

Ciccioli, Cecinato, et al., 1994
Ciccioli, P.; Cecinato, A.; Brancaleoni, E.; Brachetti, A.; Frattoni, M.; Sparapani, R., Composition and Distribution of Polar and Non-Polar VOCs in Urban, Rural, Forest and Remote Areas, Eur Commission EUR, 1994, 549-568. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas Chromatography, References

• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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