p-Benzoquinone

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Condensed phase thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-186.8 ± 0.71kJ/molCcbPilcher and Sutton, 1956ALS
Δfsolid-184.5 ± 0.63kJ/molCcbParks, Manchester, et al., 1954ALS
Δfsolid-184.5kJ/molCcbSchreiner, 1925ALS
Quantity Value Units Method Reference Comment
Δcsolid-2725.80kJ/molCcbMagnus, 1956Corresponding Δfsolid = -206.92 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-2745.9 ± 0.42kJ/molCcbPilcher and Sutton, 1956Corresponding Δfsolid = -186.8 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-2748.2kJ/molCcbParks, Manchester, et al., 1954Corresponding Δfsolid = -184.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-2748.3kJ/molCcbSchreiner, 1925Corresponding Δfsolid = -184.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-2753.kJ/molCcbSwietoslawski and Starczedska, 1925Corresponding Δfsolid = -179. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
126.4298.15Ueberreiter and Orthmann, 1950T = 293 to 368 K. Equation only.; DH
132.2298.Andrews, Lynn, et al., 1926T = 22 to 160°C.; DH
129.7291.2Lange, 1924T = 22 to 291 K. Value is unsmoothed experimental datum.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Sutton, 1956
Pilcher, G.; Sutton, L.E., The heats of combustion of quinol and p-benzoquinone and the thermodynamic quantities of the oxidation-reduction reaction, J. Chem. Soc., 1956, 2695-2700. [all data]

Parks, Manchester, et al., 1954
Parks, G.S.; Manchester, K.E.; Vaughan, L.M., Heats of combustion and formation of some alcohols, phenols, and ketones, J. Chem. Phys., 1954, 22, 2089-2090. [all data]

Schreiner, 1925
Schreiner, E., Thermodynamics of the quinhydrone electrode and the chemical constant of hydrogen, Z. Phys. Chem., 1925, 117, 57-87. [all data]

Magnus, 1956
Magnus, A., Die resonanzenergien der parachinone Aui grund der prazisionsmessungsen ihrer verbrennungswarmen durch herrn gerhard wittwer, Z. Phys. Chem. (Neue Folge), 1956, 9, 141-161. [all data]

Swietoslawski and Starczedska, 1925
Swietoslawski, W.; Starczedska, H., Correction des donnees thermochimiques de M.A. Valeur, J. Chem. Phys., 1925, 22, 399-401. [all data]

Ueberreiter and Orthmann, 1950
Ueberreiter, K.; Orthmann, H.-J., Specifische Wärme, spezifisches Volumen, Temperatur- und Wärme-leittähigkeit einiger disubstituierter Benzole und polycyclischer Systeme, Z. Natursforsch. 5a, 1950, 101-108. [all data]

Andrews, Lynn, et al., 1926
Andrews, D.H.; Lynn, G.; Johnston, J., The heat capacities and heat of crystallization of some isomeric aromatic compounds, J. Am. Chem. Soc., 1926, 48, 1274-1287. [all data]

Lange, 1924
Lange, F., Untersuchungen über die spezifische Wärme bei tiefen Temperaturen, Z. Phys. Chem., 1924, 110, 343-362. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, References