p-Cresol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-46.1kcal/molCcbPushin, 1954Author's hf298_condensed=-48.3 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Δcliquid-885.5kcal/molCcbPushin, 1954Author's hf298_condensed=-48.3 kcal/mol; Corresponding Δfliquid = -46.1 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
Δfsolid-47.61kcal/molCcbCox, 1961ALS
Δfsolid-47.64 ± 0.36kcal/molCcbAndon, Biddiscombe, et al., 1960ALS
Quantity Value Units Method Reference Comment
Δcsolid-884.02 ± 0.07kcal/molCcbCox, 1961Corresponding Δfsolid = -47.60 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-883.99 ± 0.16kcal/molCcbAndon, Biddiscombe, et al., 1960Corresponding Δfsolid = -47.63 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-885.0kcal/molCcbBarker, 1925Author was aware that data differs from previously reported values; Corresponding Δfsolid = -46.6 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar39.990cal/mol*KN/AAndon, Counsell, et al., 1967DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
39.08298.15Meva'a and Lichanot, 1990T = 173 to 353 K. Cp(c) = 145.401 + 0.616T + 3.728x10-3T2 + 2.145x10-5T3 J/mol*K (-100 to 22 C). Cp(liq) = 232.122 + 0.178T J/mol*K (40 to 80 C).; DH
52.827298.15Nichols and Wads, 1975DH
35.911298.15Andon, Counsell, et al., 1967T = 10 to 400 K.; DH
54.06313.Rastorguev and Ganiev, 1967T = 313 to 373 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pushin, 1954
Pushin, N.A., Heats of combustion and heats of formation of isomeric organic compounds, Bull. Soc. Chim. Belgrade, 1954, 19, 531-547. [all data]

Cox, 1961
Cox, J.D., The heats of combustion of phenol and the three cresols, Pure Appl. Chem., 1961, 2, 125-128. [all data]

Andon, Biddiscombe, et al., 1960
Andon, R.J.L.; Biddiscombe, D.P.; Cox, J.D.; Handley, R.; Harrop, D.; Herington, E.F.G.; Martin, J.F., Thermodynamic properties of organic oxygen compounds. Part I. Preparation and physical properties of pure phenol, cresols, and xylenols, J. Chem. Soc., 1960, 5246-5254. [all data]

Barker, 1925
Barker, M.F., Calorific value and constitution, J. Phys. Chem., 1925, 29, 1345-1363. [all data]

Andon, Counsell, et al., 1967
Andon, R.J.L.; Counsell, J.F.; Lees, E.B.; Martin, J.F.; Mash, C.J., Thermodynamic properties of organic oxygen compounds. Part 17. Low-temperature heat capacity and entropy of the cresols, Trans. Faraday Soc., 1967, 63, 1115-1121. [all data]

Meva'a and Lichanot, 1990
Meva'a, L.M.; Lichanot, A., Proprietes thermodynamiques en phase condensee des ortho, meta et para fluorotoluene, cresol et toluidine, Thermochim. Acta, 1990, 158, 335-345. [all data]

Nichols and Wads, 1975
Nichols, N.; Wads, I., Thermochemistry of solutions of biochemical model compounds. 3. Some benzene derivatives in aqueous solution, J. Chem. Thermodynam., 1975, 7, 329-336. [all data]

Rastorguev and Ganiev, 1967
Rastorguev, Yu.L.; Ganiev, Yu.A., Study of the heat capacity of selected solvents, Izv. Vyssh. Uchebn. Zaved. Neft Gaz. 10, 1967, No.1, 79-82. [all data]


Notes

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