Geranyl acetate

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Equity-5MSHP-5HP-5BP-1HP-5
Column length (m) 30.30.25.50.30.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.250.250.220.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.40.60.60.50.
Tend (C) 250.250.240.220.220.
Heat rate (K/min) 3.5.4.2.5.
Initial hold (min)  1.2. 10.
Final hold (min) 10.10. 20. 
I 1377.1383.1388.1360.1385.
ReferenceBelsito E.L., Carbone C., et al., 2007Benzo, Gilardoni, et al., 2007Dehghan, Solaimanian, et al., 2007Duquesnoy, Castola, et al., 2007Flamini, Tebano, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-1DB-5DB-5BP-1SPB-1
Column length (m) 60.30.30.50.30.
Carrier gas HeHeN2HeHe
Substrate      
Column diameter (mm) 0.220.220.250.220.2
Phase thickness (μm) 0.250.250.250.250.2
Tstart (C) 60.55.60.60.70.
Tend (C) 230.240.240.220.220.
Heat rate (K/min) 2.3.3.2.3.
Initial hold (min)  2.3.  
Final hold (min) 35.15.3.20.15.
I 1358.1382.1379.1358.1359.
ReferencePaolini J., Costa J., et al., 2007Silva, Barbosa, et al., 2007Dob, Dahmane, et al., 2006Gonny, Cavaleiro, et al., 2006Pinto, Pina-Vaz, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-1SPB-1HP-5MSDB-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.20.250.250.25
Phase thickness (μm) 0.250.20.250.250.25
Tstart (C) 50.70.60.50.50.
Tend (C) 250.220.280.250.250.
Heat rate (K/min) 5.3.4.5.5.
Initial hold (min) 3. 5.2.2.
Final hold (min) 15.15.   
I 1360.1359.1385.1381.1381.
ReferenceRadulovic, Mananjarasoa, et al., 2006Salgueiro L.R., Pinto E., et al., 2006Saroglou, Dorizas, et al., 2006Su, Ho, et al., 2006Su, Ho, et al., 2006, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSSPB-1DB-5RTX-1DB-1
Column length (m) 30.30.30.60.30.
Carrier gas H2HeHe N2
Substrate      
Column diameter (mm) 0.250.250.20.220.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.50.50.60.50.
Tend (C) 285.250.250.220.260.
Heat rate (K/min) 4.35.5.2.2.
Initial hold (min)  3.3. 3.
Final hold (min)  15.15.20.5.
I 1376.1365.1379.1360.1355.
ReferenceVujisic L., Vuckovic I., et al., 2006Boskovic, Radulovic, et al., 2005Boskovic, Radulovic, et al., 2005Cozzani, Muselli, et al., 2005Dob, Berramdane, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-1MDN-5DB-1BP-1
Column length (m) 30.30.30.30.50.
Carrier gas N2 HeHeHe
Substrate      
Column diameter (mm) 0.320.320.250.250.22
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.50.50.40.60.
Tend (C) 260.250.250.250.220.
Heat rate (K/min) 2.2.3.3.2.
Initial hold (min) 3.8.   
Final hold (min) 5.  20.20.
I 1388.1363.1375.1363.1358.
ReferenceDob T., Berramdane T., et al., 2005Dob, Dahmane, et al., 2005Dugo, Mondello, et al., 2005Fanciullino, Gancel, et al., 2005Ferrari, Tomi, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1CP Sil 5 CBRTX-1HP-5MSHP-5MS
Column length (m) 30.50.60.30.60.
Carrier gas HeH2HeHeHe
Substrate      
Column diameter (mm) 0.250.220.220.250.2
Phase thickness (μm) 0.250.130.250.250.25
Tstart (C) 40.40.60.60.60.
Tend (C) 250.300.230.250.200.
Heat rate (K/min) 3.4.2.4.2.
Initial hold (min)    2. 
Final hold (min) 20.10.35.20.10.
I 1358.1363.1358.1383.1384.
ReferenceGancel, Ollitrault, et al., 2005Idzojtic, Kajba, et al., 2005Paolini, Costa, et al., 2005Pino, Mesa, et al., 2005Smadja, Rondeau, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Mega 5MSHP-5HP-5MSRTX-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeN2HeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.60.45.60.
Tend (C) 240.220.280.300.260.
Heat rate (K/min) 3.5.3.3.3.
Initial hold (min) 2.10. 6. 
Final hold (min)    10. 
I 1379.1364.1379.1383.1383.
ReferenceVerzera, Trozzi, et al., 2005Bertoli, Pistelli, et al., 2004Chorianopoulos, Kalpoutzakis, et al., 2004Dugo, Mondello, et al., 2004Javidnia, Miri, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5MSSPB-1RSL-200BP-1
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeH2N2
Substrate      
Column diameter (mm) 0.250.250.20.320.32
Phase thickness (μm) 0.250.250.20.250.25
Tstart (C) 60.40.70.40.60.
Tend (C) 280.280.220.280.220.
Heat rate (K/min) 4.4.3.6.5.
Initial hold (min) 5.2. 5. 
Final hold (min)   15.5.13.
I 1379.1383.1359.1354.1357.
ReferenceKarioti, Hadjipavlou-Litina, et al., 2004Mardarowicz, Wianowska, et al., 2004Moldão-Martins, Beirão-da-Costa, et al., 2004Ngassoum, Ousmaila, et al., 2004Raina, Kumar, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5BP-1SBP-5DB-5MSDB-5MS
Column length (m) 25.50.60.30.30.
Carrier gas HeHeHeliumHeHe
Substrate      
Column diameter (mm) 0.20.220.250.250.25
Phase thickness (μm) 0.330.250.250.250.25
Tstart (C) 60.60.50.40.40.
Tend (C) 240.220.240.200.200.
Heat rate (K/min) 3.2.5.4.4.
Initial hold (min)   3.5.5.
Final hold (min) 7.20.10.20.20.
I 1379.1356.1352.1379.1384.
ReferenceSartoratto, Machado, et al., 2004Tam, Thuam, et al., 2004Yoo, Kim, et al., 2004Yu, Kim, et al., 2004Yu, Kim, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5MSDB-5MSDB-1SPB-1SPB-1
Column length (m) 30.30.30.30.25.
Carrier gas HeHeN2He 
Substrate      
Column diameter (mm) 0.250.250.250.20.25
Phase thickness (μm) 0.250.250.250.20.25
Tstart (C) 40.40.50.70.35.
Tend (C) 200.200.200.220.225.
Heat rate (K/min) 4.4.5.3.4.
Initial hold (min) 5.5.  10.
Final hold (min) 20.20.0.15. 
I 1381.1377.1378.1359.1365.
ReferenceYu, Kim, et al., 2004, 2Yu, Kim, et al., 2004, 2Boyom, Assembe, et al., 2003Cavaleiro, Salgueiro, et al., 2003Chisholm, Wilson, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-1DB-5DB-5HP-5
Column length (m) 30.30.30.25.30.
Carrier gas HeHeN2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.25 0.25
Tstart (C) 40.40.75.60.60.
Tend (C) 250.250.230.260.240.
Heat rate (K/min) 2.3.3.4.3.
Initial hold (min) 5. 10.  
Final hold (min)  20.   
I 1358.1358.1381.1383.1382.
Referencede Feo, Urrunaga Soria, et al., 2003Gancel, Ollitrault, et al., 2003bin Jantan, Yassin, et al., 2003Javidnia, Miri, et al., 2003Macchioni, Cioni, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5Mega 5MSDB-5DB-5BP-1
Column length (m) 30.30.30.30.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.22
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.40.70.60.60.
Tend (C) 240.240.230.260.220.
Heat rate (K/min) 3.3.4.4.2.
Initial hold (min)  2.2.  
Final hold (min)   20. 20.
I 1388.1379.1383.1383.1358.
ReferenceShellie and Marriott, 2003Verzera, Trozzi, et al., 2003Choi, Kim. M.-S.L., et al., 2002Javidnia, Miri, et al., 2002Lota, de Rocca Serra, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-5HP-1CP Sil 5 CBCP Sil 5 CBDB-1
Column length (m) 30.24.25.30.50.
Carrier gas HeHeN2H2He
Substrate      
Column diameter (mm) 0.250.320.250.250.22
Phase thickness (μm) 0.250.170.250.250.25
Tstart (C) 45.60.60.60.60.
Tend (C) 300.250.280.280.220.
Heat rate (K/min) 3.4.4.2.2.
Initial hold (min) 6.2.6.10. 
Final hold (min) 10.20. 40.20.
I 1387.1362.1359.1359.1359.
ReferenceMondello, Zappia, et al., 2002Nath, Sarma, et al., 2002Pino, Marbot, et al., 2002Pino, Marbot, et al., 2002, 2Pintore, Usai, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5RTX-5RTX-5HP-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.45.45.60.60.
Tend (C) 280.250.250.280.380.
Heat rate (K/min) 3.3.3.3.3.
Initial hold (min)  6.6.5. 
Final hold (min)      
I 1359.1383.1390.1383.1377.
ReferencePitarokili, Couladis, et al., 2002Shellie, Mondello, et al., 2002Shellie, Mondello, et al., 2002Aligiannis, Kalpoutzakis, et al., 2001Couladis, Tsortanidou, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-5 MSBP-1BP-1BP-1HP-5MS
Column length (m) 30.50.50.50.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.220.220.220.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.60.60.60.60.
Tend (C) 210.220.220.220.280.
Heat rate (K/min) 4.2.2.2.4.
Initial hold (min) 10.   5.
Final hold (min) 10.  20. 
I 1353.1358.1358.1359.1380.
ReferenceHudaib, Grazia Bellardi, et al., 2001Lota, Serra, et al., 2001Lota, Serra, et al., 2001Rezzi, Bighelli, et al., 2001Skaltsa, Mavrommati, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5BP-1BP-1RTX-5
Column length (m) 30.60.50.50.10.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.200.250.220.220.1
Phase thickness (μm) 0.250.250.250.250.1
Tstart (C) 60.40.60.60.50.
Tend (C) 180.290.230.230.350.
Heat rate (K/min) 4.4.2.2.12.3
Initial hold (min) 8.2.   
Final hold (min) 2.5.35.35. 
I 1383.1367.1358.1358.1388.
ReferenceAlonzo, Bosco, et al., 2000Bartley and Jacobs, 2000Lota, de Rocca Serra, et al., 2000Lota, de Rocca Serra, et al., 2000Mondello, Zappia, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5Mega 5MSMega 5MSBP-1BP-1
Column length (m) 30.30.30.50.50.
Carrier gas N2HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.220.22
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.40.40.60.60.
Tend (C) 230.240.240.230.230.
Heat rate (K/min) 2.3.3.2.2.
Initial hold (min)  2.2.  
Final hold (min)    35.35.
I 1381.1379.1379.1358.1358.
ReferenceSong, Sawamura, et al., 2000Verzera, la Rosa, et al., 2000Verzera, Trozzi, et al., 2000Lota, Serra, et al., 1999Lota, Serra, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1DB-1Methyl SiliconeDB-5BP-1
Column length (m) 50.30.50.30.50.
Carrier gas He N2 He
Substrate      
Column diameter (mm) 0.220.250.250.250.22
Phase thickness (μm) 0.250.250.170.250.25
Tstart (C) 60.50.80.50.60.
Tend (C) 220.220.200.250.230.
Heat rate (K/min) 2.3.2.3.2.
Initial hold (min)  3.   
Final hold (min) 20.   35.
I 1358.1358.1360.1384.1359.
ReferenceMazzoni, Tomi, et al., 1999Muselli, Hoi, et al., 1999Sumathykutty, Rao, et al., 1999Isidorov, Zenkevich, et al., 1998Mariotti, Costa, et al., 1997
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1DB-1DB-5Methyl SiliconeDB-1
Column length (m) 50.60.30.25.60.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.220.250.320.20.32
Phase thickness (μm) 0.250.25 0.30.5
Tstart (C) 60.50.80.40.40.
Tend (C) 230.250.200.200.290.
Heat rate (K/min) 2.3.52.2.4.
Initial hold (min)  5.  2.
Final hold (min) 35. 30. 5.
I 1356.1366.1381.1365.1366.
ReferenceMariotti, Tomi, et al., 1997Stashenko, Prada, et al., 1996Vahirua-Lechat, Menut, et al., 1996Píry, Príbela, et al., 1995Bartley and Foley, 1994
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5OV-101OV-101DB-5DB-1
Column length (m) 30.50.50.60.30.
Carrier gas HeN2N2He 
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm)    1. 
Tstart (C) 50.80.80.40.50.
Tend (C) 250.200.200.220.300.
Heat rate (K/min) 4.2.2.3.2.
Initial hold (min)      
Final hold (min)      
I 1377.1359.1362.1380.1360.3
ReferenceGómez, Ledbetter, et al., 1993Yang, Sugisawa, et al., 1992Yang, Sugisawa, et al., 1992Le Quere and Latrasse, 1990Chang, Sheng, et al., 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-1DB-1OV-101CP Sil 5 CB
Column length (m) 30.30.30.50.25.
Carrier gas    H2N2
Substrate      
Column diameter (mm) 0.250.250.250.320.22
Phase thickness (μm)      
Tstart (C) 50.50.50.50.70.
Tend (C) 300.300.300.200.295.
Heat rate (K/min) 2.2.2.2.4.
Initial hold (min)      
Final hold (min)      
I 1361.51360.01360.31359.1357.
ReferenceChang, Sheng, et al., 1989Chang, Sheng, et al., 1989Chang, Sheng, et al., 1989Pieribattesti, Smadja, et al., 1988Montanarella, Bos, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillary
Active phase OV-1OV-1
Column length (m) 30.30.
Carrier gas HeHe
Substrate   
Column diameter (mm) 0.50.5
Phase thickness (μm) 0.80.8
Tstart (C) 40.40.
Tend (C) 220.220.
Heat rate (K/min) 2.2.
Initial hold (min)   
Final hold (min)   
I 1361.1361.
ReferenceDe Pooter, Omar, et al., 1985De Pooter, Omar, et al., 1985
Comment MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Belsito E.L., Carbone C., et al., 2007
Belsito E.L.; Carbone C.; Di Gioia M.L.; Leggio A.; Liguoiri A.; Perri F.; Siciliano C.; Viscomi M.C., Comparison of the volatile constituents in cold-pressed bergamot oil and a volatile oil isolated by vacuum distillation, J. Agric. Food Chem., 2007, 55, 19, 7847-7851, https://doi.org/10.1021/jf070997q . [all data]

Benzo, Gilardoni, et al., 2007
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Dehghan, Solaimanian, et al., 2007
Dehghan, G.; Solaimanian, R.; Shahverdi, A.R.; Amin, G.; Abdollahi, M.; Shafiee, A., Chemical composition and antimicrobial activity of essential oil of Ferula szovitsiana D.C., Flavour Fragr. J., 2007, 22, 3, 224-227, https://doi.org/10.1002/ffj.1789 . [all data]

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Flamini, Tebano, et al., 2007
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Paolini J., Costa J., et al., 2007
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Silva, Barbosa, et al., 2007
Silva, C.J.; Barbosa, L.C.A.; Maltha, C.R.A.; Pinheiro, A.L.; Ismail, F.M.D., Comparative study of the essential oils of seven Melaleuca (Myrtaceae) species grown in Brazil, Flavour Fragr. J., 2007, 22, 6, 474-478, https://doi.org/10.1002/ffj.1823 . [all data]

Dob, Dahmane, et al., 2006
Dob, T.; Dahmane, D.; Agli, M.; Chelghoum, C., Essential oil composition of Lavandula stoechas from Algeria, Pharm. Biol., 2006, 44, 1, 60-64, https://doi.org/10.1080/13880200500496421 . [all data]

Gonny, Cavaleiro, et al., 2006
Gonny, M.; Cavaleiro, C.; Salgueiro, L.; Casanova, J., Analysis of Juniperus communis subsp. alpina needle, berry, wood and root oils by combination of GC, GC/MS and 13C-NMR, Flavour Fragr. J., 2006, 21, 1, 99-106, https://doi.org/10.1002/ffj.1527 . [all data]

Pinto, Pina-Vaz, et al., 2006
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Radulovic, Mananjarasoa, et al., 2006
Radulovic, N.; Mananjarasoa, E.; Harinantenaina, L.; Yoshinori, A., Essential oil composition of four Croton species from Madagascar and their chemotaxonomy, Biochem. Syst. Ecol., 2006, 34, 8, 648-653, https://doi.org/10.1016/j.bse.2006.02.005 . [all data]

Salgueiro L.R., Pinto E., et al., 2006
Salgueiro L.R.; Pinto E.; Goncalves M.J.; Costa I.; Palmeira A.; Cavaleiro C.; Pina-Vaz C.; Rodrigues A.G.; Martinez-De-Oliveira J., Antifungal activity of the essential oil of Thymus capitellatus against Candida, Aspergillus and dermatophyte strains, Flavour Fragr. J., 2006, 21, 5, 749-753, https://doi.org/10.1002/ffj.1610 . [all data]

Saroglou, Dorizas, et al., 2006
Saroglou, V.; Dorizas, N.; Kypriotakis, Z.; Skaltsa, H.D., Analysis of the essential oil composition of eight Anthemis species from Greece, J. Chromatogr. A, 2006, 1104, 1-2, 313-322, https://doi.org/10.1016/j.chroma.2005.11.087 . [all data]

Su, Ho, et al., 2006
Su, Y.C.; Ho, C.L.; Wang, E.I.C., Analysis of leaf essential oils from the indigenous five conifers of Taiwan, Flavour Fragr. J., 2006, 21, 3, 447-452, https://doi.org/10.1002/ffj.1685 . [all data]

Su, Ho, et al., 2006, 2
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Notes

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