2-Hexanone, 4-methyl-

• Formula: C₇H₁₄O
• Molecular weight: 114.1855
• IUPAC Standard InChI: InChI=1S/C7H14O/c1-4-6(2)5-7(3)8/h6H,4-5H2,1-3H3 Copy

  
• IUPAC Standard InChIKey: XUPXMIAWKPTZLZ-UHFFFAOYSA-N Copy
• CAS Registry Number: 105-42-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Methyl 2-methylbutyl ketone; 4-Methyl-2-hexanone; 4-Methylhexan-2-one
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• Information on this page:
  • Normal boiling point
  • References
  • Notes
• Other data available:
  • Phase change data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
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Normal boiling point

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Djerassi and Geller, 1959
Djerassi, C.; Geller, L.E., Optical rotary dispersion studies: xxiv effect of distance of a single asymmetric center from an aliphatic carbonyl function, J. Am. Chem. Soc., 1959, 81, 2789. [all data]

Brokaw and Brode, 1948
Brokaw, G.Y.; Brode, W.R., Asymmetric induction and racemization in compounds containing the optically active 2-methylbutyl (active amyl) radical, J. Org. Chem., 1948, 13, 194. [all data]

Cymerman, Heilbron, et al., 1945
Cymerman, J.; Heilbron, I.M.; Jones, E.R.H., Studies in the polyene series: xxi ethynylcarbinols from alpha,beta- unsaturated ketones their anionotropic rearrangements and other reactions, J. Chem. Soc., 1945, 1945, 90. [all data]

Rhinesmith, 1936
Rhinesmith, H.S., Semicarbazones of Certain Ketones, J. Am. Chem. Soc., 1936, 58, 596. [all data]

Johnson and Hager, 1927
Johnson; Hager, Org. Synth., 1927, 7, 60. [all data]

Kohler, 1907
Kohler, Am. Chem. J., 1907, 38, 511. [all data]

Notes

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• Symbols used in this document:
  

  Tboil

  Boiling point

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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