Germane, tetraphenyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas104.8 ± 3.5kcal/molReviewMartinho SimõesSelected data
Δfgas245.7 ± 1.7kcal/molReviewMartinho Simões 
Δfgas143.8 ± 2.4kcal/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub37.5 ± 1.0kcal/molN/APilcher and Skinner, 1983See also Adams, Carson, et al., 1969.; AC
Δsub40.3 ± 2.0kcal/molN/APilcher and Skinner, 1983See also Carson, Carson, et al., 1970.; AC
Δsub37.5 ± 1.0kcal/molCC-RBKana'an, 1974MS

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
35.52441.AStephenson and Malanowski, 1987Based on data from 402. to 480. K.; AC

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-IW-4531
NIST MS number 236293

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References

Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Adams, Carson, et al., 1969
Adams, G.P.; Carson, A.S.; Laye, P.G., Heats of combustion of organo-metallic compounds using a vacuum-jacketed, rotating, aneroid calorimeter. Heat of formation of germanium tetraphenyl, Trans. Faraday Soc., 1969, 65, 113, https://doi.org/10.1039/tf9696500113 . [all data]

Carson, Carson, et al., 1970
Carson, A.S.; Carson, E.M.; Laye, P.G.; Spencer, J.A.; Steele, W.V., Enthalpy of combustion of organo-metallic compounds measured with a vacuum-jacketed, rotating, aneroid calorimeter. The enthalpies of formation of germanium tetrabenzyl and di-germanium hexaphenyl, Trans. Faraday Soc., 1970, 66, 2459, https://doi.org/10.1039/tf9706602459 . [all data]

Kana'an, 1974
Kana'an, A.S., J. Chem. Thermodyn., 1974, 6, 191. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References