Uracil, 2TMS derivative

• Formula: C₁₀H₂₀N₂O₂Si₂
• Molecular weight: 256.4490
• IUPAC Standard InChI: InChI=1S/C10H20N2O2Si2/c1-15(2,3)13-9-7-8-11-10(12-9)14-16(4,5)6/h7-8H,1-6H3 Copy

  
• IUPAC Standard InChIKey: FSBNTQRWSOTNEW-UHFFFAOYSA-N Copy
• CAS Registry Number: 10457-14-4
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Pyrimidine, 2,4-bis[(trimethylsilyl)oxy]-; Pyrimidine, 2,4-bis(trimethylsiloxy)-; Bis(O-trimethylsilyl)uracil; 2,4-Bis(trimethylsiloxy)pyrimidine; 2,4-Bis(trimethylsilyl)uracil; 2,4-Bis(trimethylsilyloxy)pyrimidine; 2,4-O-Bis(trimethylsilyl)uracil; Uracil, di(trimethylsilyl) deriv.; Uracil, bis-TMS; Uracil, diTMS; Uracil bis(trimethylsilyl) ether; Uracil, TMS; Pyrimidine, 2,4-dihydroxy, TMS
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• Information on this page:
  • Mass spectrum (electron ionization)
  • Gas Chromatography
  • References
  • Notes
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Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Kovats' RI, non-polar column, custom temperature program

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Van Den Dool and Kratz RI, non-polar column, custom temperature program

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Miller, Pacáková, et al., 1976
Miller, V.; Pacáková, V.; Smolková, E., Gas-liquid chromatographic analysis of trimethylsilyl derivatives of pyrimidine and purine bases and nucleosides, J. Chromatogr., 1976, 119, 355-367, https://doi.org/10.1016/S0021-9673(00)86799-0 . [all data]

Pacakova, Miller, et al., 1971
Pacakova, V.; Miller, V.; Cernohorsky, I.J., Gas-Liquid Chromatography of Some Pyrimidine Derivatives, Anal. Biochemistry, 1971, 42, 2, 549-554, https://doi.org/10.1016/0003-2697(71)90071-6 . [all data]

Yamaji, Kimura, et al., 1978
Yamaji, A.; Kimura, S.; Kawasaki, H.; Yuki, H., Gas chromatographic analysis of pyrimidine and purine bases by retention indices, Yakugaku Zasshi, 1978, 98, 1, 1536-1541. [all data]

Ohie, Fu, et al., 2000
Ohie, T.; Fu, X.; Iga, M.; Kimura, M.; Yamaguchi, S., Gas chromatography-mass spectrometry with tert .-butyldimethylsilyl derivatization: use of the simplified sample preparations and the automated data system to screen for organic acidemias, J. Chromatogr. B, 2000, 746, 1, 63-73, https://doi.org/10.1016/S0378-4347(00)00105-5 . [all data]

Kimura, Yamamoto, et al., 1999
Kimura, M.; Yamamoto, T.; Yamaguchi, S., Automated metabolic profiling and interpretation of GC/MS data for organic acidemia screening: a personal computer-based system, Tohoku J. Exp. Med., 1999, 188, 4, 317-334, https://doi.org/10.1620/tjem.188.317 . [all data]

Butts, 1972
Butts, W.C., Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds, Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3 . [all data]

Andriamaharavo, 2014
Andriamaharavo, N.R., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2014. [all data]

Butts, 1970
Butts, W.C., Gas chromatographic separation of trimethylsilyl (TMS)-nucleosides: TMS-methoxime derivatives of cytidine and deoxycytidine, J. Chromatogr. Sci., 1970, 8, 8, 474-476, https://doi.org/10.1093/chromsci/8.8.474 . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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