samarium (III) chloride hexahydrate
- Formula: Cl3Sm
- Molecular weight: 256.72
- CAS Registry Number: 10361-82-7
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
+ Cl3Sm = Cl4Sm-
By formula: Cl- + Cl3Sm = Cl4Sm-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 69.1 ± 3.8 | kcal/mol | TDEq | Khasanshin, Pogrebnoi, et al., 1998 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
| ΔrH° | 86.5 ± 5.0 | kcal/mol | TDEq | Kudin, Vorob'ev, et al., 2007 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Khasanshin, Pogrebnoi, et al., 1998
Khasanshin, I.V.; Pogrebnoi, A.M.; Kudin, L.S.; Kuznetsov, A.Y.; Butman, M.F.,
The Neutral and Ionic Components of Saturated Vapor of Samarium Dichloride: The Thermochemical Characteristics of Gaseous Molecules and Ions,
High Temp., 1998, 36, 687-694. [all data]
Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E.,
The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions,
Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X
. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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