(Z)-3-Phenyl-2-propenoic acid


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δcsolid-4383.8 ± 1.7kJ/molCcbEisenlohr and Metzner, 1937Reanalyzed by Cox and Pilcher, 1970, Original value = -4377.7 kJ/mol; Solid m.p 68 °C; Corresponding Δfsolid = -301.1 kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcsolid-4368.0 ± 1.7kJ/molCcbEisenlohr and Metzner, 1937Reanalyzed by Cox and Pilcher, 1970, Original value = -4363.1 kJ/mol; Solid m.p 42°C; Corresponding Δfsolid = -316.9 kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcsolid-4373.7 ± 1.7kJ/molCcbEisenlohr and Metzner, 1937Reanalyzed by Cox and Pilcher, 1970, Original value = -4368.5 kJ/mol; Solid m.p 58°C; Corresponding Δfsolid = -311.2 kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcsolid-4366.0 ± 1.7kJ/molCcbEisenlohr and Hass, 1935Reanalyzed by Cox and Pilcher, 1970, Original value = -4362.7 kJ/mol; Corresponding Δfsolid = -318.9 kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcsolid-4385.3kJ/molCcbRoth and Stoermer, 1913Corresponding Δfsolid = -300. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference
16.95341.2Acree, 1991

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Eisenlohr and Metzner, 1937
Eisenlohr, F.; Metzner, A., Uber die cis-zimtsauren. I, Z. Phys. Chem., 1937, 178, 339-349. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Eisenlohr and Hass, 1935
Eisenlohr, F.; Hass, W., Uber die cis-zimtsaure, Z. Phys. Chem., 1935, 173, 249-264. [all data]

Roth and Stoermer, 1913
Roth, W.A.; Stoermer, R., Physikalisch-chemische untersuchungen an aromatischen stereoisomeren sauren 1, Chem. Ber., 1913, 40, 260-280. [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]


Notes

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