Aluminum, tripropyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-234. ± 16.kJ/molReviewMartinho SimõesLiquid tripropylaluminum contains a very small molar fraction of monomer at 298 K, ca. 0.5% Smith, 1974, so that the "real" liquid should be described as [Al(Pr)3]2.
Δfgas-279.8 ± 1.9kJ/molReviewMartinho SimõesLiquid tripropylaluminum contains a very small molar fraction of monomer at 298 K, ca. 0.5% Smith, 1974, so that the "real" liquid should be described as [Al(Pr)3]2.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C18H42Al2 (l) = 2Aluminum, tripropyl- (l)

By formula: C18H42Al2 (l) = 2C9H21Al (l)

Quantity Value Units Method Reference Comment
Δr64.5 ± 0.8kJ/molEqSSmith, 1974 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Smith, 1974
Smith, M.B., J. Organometal. Chem., 1974, 70, 13. [all data]


Notes

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