Aluminum, tripropyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-66.0 ± 3.8kcal/molReviewMartinho SimõesLiquid tripropylaluminum contains a very small molar fraction of monomer at 298 K, ca. 0.5% Smith, 1974, so that the "real" liquid should be described as [Al(Pr)3]2.; MS
Δfliquid-77.03 ± 0.36kcal/molReviewMartinho SimõesLiquid tripropylaluminum contains a very small molar fraction of monomer at 298 K, ca. 0.5% Smith, 1974, so that the "real" liquid should be described as [Al(Pr)3]2.; MS
Quantity Value Units Method Reference Comment
Δcliquid-1698.0 ± 3.8kcal/molCC-SBShmyreva, Sakharovskaya, et al., 1971Please also see Pedley and Rylance, 1977.; MS
Δcliquid-1687.0 ± 0.1kcal/molCC-SBPawlenko, 1967Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS
Quantity Value Units Method Reference Comment
liquid88.46cal/mol*KN/ASheiman, Rabinovich, et al., 1991DH
liquid88.46cal/mol*KN/ASheiman, Nistratov, et al., 1984DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
81.38298.15Sheiman, Rabinovich, et al., 1991T = 14 to 327 K.; DH
81.38298.15Sheiman, Nistratov, et al., 1984T = 5 to 300 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Smith, 1974
Smith, M.B., J. Organometal. Chem., 1974, 70, 13. [all data]

Shmyreva, Sakharovskaya, et al., 1971
Shmyreva, G.O.; Sakharovskaya, G.B.; Popov, A.F.; Korneev, N.N.; Smolyaninova, A.A., Russ. J. Phys. Chem., 1971, 45, 260. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Pawlenko, 1967
Pawlenko, S., Chem. Ber., 1967, 100, 3591. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Sheiman, Rabinovich, et al., 1991
Sheiman, M.S.; Rabinovich, I.B.; Nistratov, V.P.; Smirnova, N.N.; Kamelova, G.P.; Klimov, K.N.; Zorin, A.D., Low temperature heat capacity and thermodynamic functions of tripropylaluminum and diisobutylaluminum, Zhur. Fiz. Khim., 1991, 65(3), 831-836. [all data]

Sheiman, Nistratov, et al., 1984
Sheiman, M.S.; Nistratov, V.P.; Kamelova, G.P.; Rabinovich, I.B., Low-temperature heat capacity of organic compounds of aluminum and zinc, Probl. Kalorim. Khim. Termodin., Dokl. Vses. Konf., 10th, 1984, 2, 457-459. [all data]


Notes

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