Naphth-2-yl


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C10H6- + Hydrogen cation = Naphth-2-yl

By formula: C10H6- + H+ = C10H7

Quantity Value Units Method Reference Comment
Δr1577. ± 13.kJ/molG+TSReed, Hare, et al., 2000gas phase; Between tBuOD and 1-pentyne
Quantity Value Units Method Reference Comment
Δr1545. ± 13.kJ/molIMRBReed, Hare, et al., 2000gas phase; Between tBuOD and 1-pentyne

C10H6- + Hydrogen cation = Naphth-2-yl

By formula: C10H6- + H+ = C10H7

Quantity Value Units Method Reference Comment
Δr1633. ± 17.kJ/molG+TSReed, Hare, et al., 2000gas phase
Quantity Value Units Method Reference Comment
Δr1600. ± 17.kJ/molIMRBReed, Hare, et al., 2000gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

View reactions leading to C10H7+ (ion structure unspecified)

De-protonation reactions

C10H6- + Hydrogen cation = Naphth-2-yl

By formula: C10H6- + H+ = C10H7

Quantity Value Units Method Reference Comment
Δr1577. ± 13.kJ/molG+TSReed, Hare, et al., 2000gas phase; Between tBuOD and 1-pentyne
Quantity Value Units Method Reference Comment
Δr1545. ± 13.kJ/molIMRBReed, Hare, et al., 2000gas phase; Between tBuOD and 1-pentyne

C10H6- + Hydrogen cation = Naphth-2-yl

By formula: C10H6- + H+ = C10H7

Quantity Value Units Method Reference Comment
Δr1633. ± 17.kJ/molG+TSReed, Hare, et al., 2000gas phase
Quantity Value Units Method Reference Comment
Δr1600. ± 17.kJ/molIMRBReed, Hare, et al., 2000gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reed, Hare, et al., 2000
Reed, D.R.; Hare, M.; Kass, S.R., Formation of gas-phase dianions and distonic ions as a general method for the synthesis of protected reactive intermediates. Energetics of 2,3-and 2,6-dehydronaphthalene, J. Am. Chem. Soc., 2000, 122, 43, 10689-10696, https://doi.org/10.1021/ja002351j . [all data]


Notes

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