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erbium trichloride

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Chlorine anion + Cl3Er = Cl4Er-

By formula: Cl- + Cl3Er = Cl4Er-

Quantity Value Units Method Reference Comment
Deltar344. ± 21.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Deltar327. ± 16.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale

Chlorine anion + Cl3Er = Cl7Er2-

By formula: Cl- + Cl3Er = Cl7Er2-

Quantity Value Units Method Reference Comment
Deltar239. ± 37.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Deltar340. ± 37.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale

Cl10Er3- + Cl3Er = Cl19Er6-

By formula: Cl10Er3- + Cl3Er = Cl19Er6-

Quantity Value Units Method Reference Comment
Deltar390. ± 63.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; Affinity taken as Er3Cl9..Er3Cl10-; value altered from reference due to change in acidity scale

Cl4Er- + Cl3Er = Cl13Er4-

By formula: Cl4Er- + Cl3Er = Cl13Er4-

Quantity Value Units Method Reference Comment
Deltar330. ± 63.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; Affinity taken as Er3Cl9..ErCl4-; value altered from reference due to change in acidity scale

Chlorine anion + Cl3Er = Cl10Er3-

By formula: Cl- + Cl3Er = Cl10Er3-

Quantity Value Units Method Reference Comment
Deltar330. ± 59.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Pogrebnoi, Motalov, et al., 2002
Pogrebnoi, A.M.; Motalov, V.B.; Kuznetsov, A.Y.; Kudin, L.S.; Khasanshin, I.V., Molecular and ionic associates in the saturated vapor over erbium trichloride and the ErCl3-DyCl3 system, Russ. J. Inorg. Chem., 2002, 47, 96-100. [all data]


Notes

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