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lutetium trichloride

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Cl3Lu = (Chlorine anion bullet Cl3Lu)

By formula: Cl- + Cl3Lu = (Cl- bullet Cl3Lu)

Quantity Value Units Method Reference Comment
Deltar297. ± 15.kJ/molTDAsPogrebnoi, Kudion, et al., 1997gas phase; EA estimated as 3.7±1.0 eV; value altered from reference due to conversion from electron convention to ion convention
Deltar359. ± 10.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention

Cl4Lu- + Cl3Lu = Cl7Lu2-

By formula: Cl4Lu- + Cl3Lu = Cl7Lu2-

Quantity Value Units Method Reference Comment
Deltar207. ± 10.kJ/molTDAsPogrebnoi, Kudion, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention
Deltar256. ± 33.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention

Cl7Lu2- + 2Cl3Lu = Cl10Lu3-

By formula: Cl7Lu2- + 2Cl3Lu = Cl10Lu3-

Quantity Value Units Method Reference Comment
Deltar242. ± 32.kJ/molTDAsPogrebnoi, Kudion, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention

Cl10Lu3- + 3Cl3Lu = Cl13Lu4-

By formula: Cl10Lu3- + 3Cl3Lu = Cl13Lu4-

Quantity Value Units Method Reference Comment
Deltar315. ± 22.kJ/molTDAsPogrebnoi, Kudion, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention

Cl13Lu4- + 4Cl3Lu = Cl16Lu5-

By formula: Cl13Lu4- + 4Cl3Lu = Cl16Lu5-

Quantity Value Units Method Reference Comment
Deltar190. ± 79.kJ/molTDAsPogrebnoi, Kudion, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention

Cl16Lu5- + 5Cl3Lu = Cl19Lu6-

By formula: Cl16Lu5- + 5Cl3Lu = Cl19Lu6-

Quantity Value Units Method Reference Comment
Deltar400. ± 96.kJ/molTDAsPogrebnoi, Kudion, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pogrebnoi, Kudion, et al., 1997
Pogrebnoi, A.; Kudion, L.S.; Kuznetsov, A.Yu.; Butman, M.F., Molecular and Ionic Clusters in Saturated Vapor over Lutetium Trichloride, Rapid Commun. Mass Spectrom., 1997, 11, 14, 1536, https://doi.org/10.1002/(SICI)1097-0231(199709)11:14<1536::AID-RCM31>3.0.CO;2-D . [all data]

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]


Notes

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