lanthanum chloride, anhydrous


Reaction thermochemistry data

Go To: Top, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Cl4La- + Cl3La = Cl7La2-

By formula: Cl4La- + Cl3La = Cl7La2-

Quantity Value Units Method Reference Comment
Δr239. ± 41.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Δr194. ± 34.kJ/molTDAsButman, Kudin, et al., 1987gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Cl3La = (Chlorine anion • Cl3La)

By formula: Cl- + Cl3La = (Cl- • Cl3La)

Quantity Value Units Method Reference Comment
Δr332. ± 17.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

(Chlorine anion • Cl3La) + Cl3La = (Chlorine anion • 2Cl3La)

By formula: (Cl- • Cl3La) + Cl3La = (Cl- • 2Cl3La)

Quantity Value Units Method Reference Comment
Δr136. ± 15.kJ/molMSButman, Kudin, et al., 1987gas phase; Knudsen cell; M

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Cl3La = (Chlorine anion • Cl3La)

By formula: Cl- + Cl3La = (Cl- • Cl3La)

Quantity Value Units Method Reference Comment
Δr332. ± 17.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

(Chlorine anion • Cl3La) + Cl3La = (Chlorine anion • 2Cl3La)

By formula: (Cl- • Cl3La) + Cl3La = (Cl- • 2Cl3La)

Quantity Value Units Method Reference Comment
Δr136. ± 15.kJ/molMSButman, Kudin, et al., 1987gas phase; Knudsen cell; M

Cl4La- + Cl3La = Cl7La2-

By formula: Cl4La- + Cl3La = Cl7La2-

Quantity Value Units Method Reference Comment
Δr239. ± 41.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Δr194. ± 34.kJ/molTDAsButman, Kudin, et al., 1987gas phase; value altered from reference due to conversion from electron convention to ion convention; B

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Butman, Kudin, et al., 1987
Butman, M.F.; Kudin, L.S.; Burdukovskaya, G.G.; Krasnov, K.S.; Bozhko, N.V., Mass Spectrometric Determination of the Enthalpy of Formation of the Gaseous Ions LaCl4- and La2Cl7-, Russ. J. Phys. Chem., 1987, 61, 1518. [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References