Benzene, (methylthio)-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C7H7S- + Hydrogen cation = Benzene, (methylthio)-

By formula: C7H7S- + H+ = C7H8S

Quantity Value Units Method Reference Comment
Deltar1616. ± 21.kJ/molG+TSIngemann and Nibbering, 1985gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar1586. ± 21.kJ/molIMRBIngemann and Nibbering, 1985gas phase; value altered from reference due to change in acidity scale

C7H7S- + Hydrogen cation = Benzene, (methylthio)-

By formula: C7H7S- + H+ = C7H8S

Quantity Value Units Method Reference Comment
Deltar1596. ± 8.8kJ/molG+TSIngemann and Nibbering, 1985gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar1566. ± 8.4kJ/molIMREIngemann and Nibbering, 1985gas phase; value altered from reference due to change in acidity scale

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ingemann and Nibbering, 1985
Ingemann, S.; Nibbering, N.M.M., Gas phase chemistry of alpha-thio carbanions, Can. J. Chem., 1985, 62, 2273. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References