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Anisole

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Bromine anion + Anisole = (Bromine anion bullet Anisole)

By formula: Br- + C7H8O = (Br- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar49.4 ± 7.5kJ/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar14. ± 4.2kJ/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
14.423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

C7H7O- + Hydrogen cation = Anisole

By formula: C7H7O- + H+ = C7H8O

Quantity Value Units Method Reference Comment
Deltar1679. ± 13.kJ/molG+TSDahlke and Kass, 1992gas phase; Acid: anisole. Between o-methoxyphenide and Me2NH.; B
Quantity Value Units Method Reference Comment
Deltar1648. ± 13.kJ/molIMRBDahlke and Kass, 1992gas phase; Acid: anisole. Between o-methoxyphenide and Me2NH.; B

C7H7O- + Hydrogen cation = Anisole

By formula: C7H7O- + H+ = C7H8O

Quantity Value Units Method Reference Comment
Deltar1666. ± 13.kJ/molG+TSDahlke and Kass, 1992gas phase; Acid: anisole. Between HO- and m,p-methoxyphenide; B
Quantity Value Units Method Reference Comment
Deltar1636. ± 13.kJ/molIMRBDahlke and Kass, 1992gas phase; Acid: anisole. Between HO- and m,p-methoxyphenide; B

C7H7O- + Hydrogen cation = Anisole

By formula: C7H7O- + H+ = C7H8O

Quantity Value Units Method Reference Comment
Deltar1681. ± 13.kJ/molG+TSDahlke and Kass, 1992gas phase; Acid: anisole. Between o-OMe-phenide and Me2NH.; B
Quantity Value Units Method Reference Comment
Deltar1648. ± 13.kJ/molIMRBDahlke and Kass, 1992gas phase; Acid: anisole. Between o-OMe-phenide and Me2NH.; B

Chlorine anion + Anisole = (Chlorine anion bullet Anisole)

By formula: Cl- + C7H8O = (Cl- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar30.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
31.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Hydrogen iodide + p-Iodoanisole = Anisole + Iodine

By formula: HI + C7H7IO = C7H8O + I2

Quantity Value Units Method Reference Comment
Deltar-29. ± 5.0kJ/molCmBrennan and Ubbelohde, 1956gas phase; ALS

(Lithium ion (1+) bullet Anisole) + Anisole = (Lithium ion (1+) bullet 2Anisole)

By formula: (Li+ bullet C7H8O) + C7H8O = (Li+ bullet 2C7H8O)

Quantity Value Units Method Reference Comment
Deltar121. ± 4.kJ/molCIDTAmunugama and Rodgers, 2003RCD

(Sodium ion (1+) bullet Anisole) + Anisole = (Sodium ion (1+) bullet 2Anisole)

By formula: (Na+ bullet C7H8O) + C7H8O = (Na+ bullet 2C7H8O)

Quantity Value Units Method Reference Comment
Deltar90. ± 3.kJ/molCIDTAmunugama and Rodgers, 2003RCD

(Cesium ion (1+) bullet Anisole) + Anisole = (Cesium ion (1+) bullet 2Anisole)

By formula: (Cs+ bullet C7H8O) + C7H8O = (Cs+ bullet 2C7H8O)

Quantity Value Units Method Reference Comment
Deltar62. ± 4.kJ/molCIDTAmunugama and Rodgers, 2003RCD

(Rubidium ion (1+) bullet Anisole) + Anisole = (Rubidium ion (1+) bullet 2Anisole)

By formula: (Rb+ bullet C7H8O) + C7H8O = (Rb+ bullet 2C7H8O)

Quantity Value Units Method Reference Comment
Deltar64. ± 3.kJ/molCIDTAmunugama and Rodgers, 2003RCD

(Potassium ion (1+) bullet Anisole) + Anisole = (Potassium ion (1+) bullet 2Anisole)

By formula: (K+ bullet C7H8O) + C7H8O = (K+ bullet 2C7H8O)

Quantity Value Units Method Reference Comment
Deltar70. ± 3.kJ/molCIDTAmunugama and Rodgers, 2003RCD

Lithium ion (1+) + Anisole = (Lithium ion (1+) bullet Anisole)

By formula: Li+ + C7H8O = (Li+ bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar185. ± 19.kJ/molCIDTAmunugama and Rodgers, 2003RCD

Sodium ion (1+) + Anisole = (Sodium ion (1+) bullet Anisole)

By formula: Na+ + C7H8O = (Na+ bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar113. ± 8.4kJ/molCIDTAmunugama and Rodgers, 2003RCD

Cesium ion (1+) + Anisole = (Cesium ion (1+) bullet Anisole)

By formula: Cs+ + C7H8O = (Cs+ bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar66.5 ± 5.0kJ/molCIDTAmunugama and Rodgers, 2003RCD

Rubidium ion (1+) + Anisole = (Rubidium ion (1+) bullet Anisole)

By formula: Rb+ + C7H8O = (Rb+ bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar72.4 ± 4.2kJ/molCIDTAmunugama and Rodgers, 2003RCD

Potassium ion (1+) + Anisole = (Potassium ion (1+) bullet Anisole)

By formula: K+ + C7H8O = (K+ bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar79. ± 3.kJ/molCIDTAmunugama and Rodgers, 2003RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Paul and Kebarle, 1991
Paul, G.J.C.; Kebarle, P., Stabilities of Complexes of Br- with Substituted Benzenes (SB) Based on Determinations of the Gas-Phase Equilibria Br- + SB = (BrSB)-, J. Am. Chem. Soc., 1991, 113, 4, 1148, https://doi.org/10.1021/ja00004a014 . [all data]

Dahlke and Kass, 1992
Dahlke, G.D.; Kass, S.R., The Ortho-dehydrophenoxy Anion, Int. J. Mass Spectrom. Ion Proc., 1992, 117, 633, https://doi.org/10.1016/0168-1176(92)80117-J . [all data]

French, Ikuta, et al., 1982
French, M.A.; Ikuta, S.; Kebarle, P., Hydrogen bonding of O-H and C-H hydrogen donors to Cl-. Results from mass spectrometric measurement of the ion-molecule equilibria RH + Cl- = RHCl-, Can. J. Chem., 1982, 60, 1907. [all data]

Brennan and Ubbelohde, 1956
Brennan, D.; Ubbelohde, A.R., A thermochemical evaluation of bond strengths in some carbon compounds. Part IV. Bond-strength differences based on the reaction: RI + HI = RH + I2, where R = p-methoxyphenyl and cyclohexyl, J. Chem. Soc., 1956, 3011-3016. [all data]

Amunugama and Rodgers, 2003
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions - 5. Absolute binding energies of alkali metal cation-anisole complexes determined by threshold collision-induced dissociation and theoretical studies, Int. J. Mass Spectrom., 2003, 222, 1-3, 431, https://doi.org/10.1016/S1387-3806(02)00945-4 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References