Aniline, N-methyl-
- Formula: C7H9N
- Molecular weight: 107.1531
- IUPAC Standard InChI: InChI=1S/C7H9N/c1-8-7-5-3-2-4-6-7/h2-6,8H,1H3
- IUPAC Standard InChIKey: AFBPFSWMIHJQDM-UHFFFAOYSA-N
- CAS Registry Number: 100-61-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: (Methylamino)benzene; Benzenamine, N-methyl-; Anilinomethane; Methylphenylamine; N-Methylaniline; N-Methylbenzenamine; N-Methylphenylamine; N-Monomethylaniline; N-Phenylmethylamine; N-Methylaminobenzene; Monomethylaniline; Methylaniline; Benzeneamine, N-methyl-; UN 2294; NSC 3502
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | 33.4 ± 7.5 | kJ/mol | Cm | Guthrie, Barker, et al., 1993 | ALS |
| ΔfH°liquid | 32. | kJ/mol | Ccb | Vriens and Hill, 1952 | ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -4073. | kJ/mol | Ccb | Vriens and Hill, 1952 | ALS |
| ΔcH°liquid | -4077. | kJ/mol | Ccb | Garner and Abernethy, 1921 | ALS |
Constant pressure heat capacity of liquid
| Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 207.1 | 298. | Lesbats and Lichanot, 1987 | T = 220 to 325 K.; DH |
| 230.1 | 290. | Kurnakov and Voskresenskaya, 1936 | DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Guthrie, Barker, et al., 1993
Guthrie, J.P.; Barker, J.; Cullimore, P.A.; Lu, J.; Pike, D.C.,
The tetrahedral intermediate from the hydration of N-methylformanilide,
Can. J. Chem., 1993, 71, 2111-2122. [all data]
Vriens and Hill, 1952
Vriens, G.N.; Hill, A.G.,
Equilibria of several reactions of aromatic amines,
Ind. Eng. Chem., 1952, 44, 2732-27. [all data]
Garner and Abernethy, 1921
Garner, W.E.; Abernethy, C.L.,
Heats of combustion and formation of nitro-compounds. Part I. - Benzene, toluene, phenol and methylaniline series,
Proc. Roy. Soc. London A, 1921, 213-235. [all data]
Lesbats and Lichanot, 1987
Lesbats, C.; Lichanot, A.,
Capacites calorifiques de durcisseurs amines et resines epoxydes,
Thermochim. Acta, 1987, 109, 317-329. [all data]
Kurnakov and Voskresenskaya, 1936
Kurnakov, N.S.; Voskresenskaya, N.K.,
Calorimetry of liquid binary systems, Izv. Akad. Nauk SSSR,
Otdel. Mat. i Estestv. Nauk. Ser. Khim, 1936, 1936, 439-461. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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