Mercury, chlorophenyl-

Formula: C₆H₅ClHg
Molecular weight: 313.15
IUPAC Standard InChI: InChI=1S/C6H5.ClH.Hg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
IUPAC Standard InChIKey: AWGTVRDHKJQFAX-UHFFFAOYSA-M
CAS Registry Number: 100-56-1
Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript.
Other names: Agrenal; Agronal; Benzene, (chloromercurio)-; Chlorophenylmercury; Hexason; Merfazin; Mersolite 2; Phenyl chloromercury; Phenylmercuric chloride; Phenylmercury chloride; PMC; Phenylmercury(II) chloride; Benzene, (chloromercuri)-; Chlorid fenylrtutnaty; (Chloromercuri)benzene; Fenylmercurichlorid; Mercuriphenyl chloride; Phenylquecksilberchlorid; Stopspot; Mercutal; Monophenylmercury chloride; PMC (fungicide)
Permanent link for this species. Use this link for bookmarking this species for future reference.
Information on this page:
Other data available:
- Gas phase ion energetics data
- Mass spectrum (electron ionization)
Data at other public NIST sites:
- Gas Phase Kinetics Database
Options:
- Switch to SI units

Condensed phase thermochemistry data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compiled by: José A. Martinho Simões

Quantity	Value	Units	Method	Reference	Comment
Δ_fH°_solid	0.8 ± 1.5	kcal/mol	Review	Martinho Simões	The enthalpy of formation relies on 67.3 ± 1.3 kcal/mol for the enthalpy of formation of Hg(Ph)2(l).
Δ_fH°_solid	-0.84 ± 0.88	kcal/mol	Review	Martinho Simões	The enthalpy of formation relies on 67.3 ± 1.3 kcal/mol for the enthalpy of formation of Hg(Ph)2(l).
Δ_fH°_solid	0.0 ± 0.84	kcal/mol	Review	Martinho Simões

Reaction thermochemistry data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(l) + Cl₂Hg (cr) = 2 Mercury, chlorophenyl- (cr)

By formula: C₁₂H₁₀Hg (l) + Cl₂Hg (cr) = 2C₆H₅ClHg (cr)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	-13.9 ± 0.50	kcal/mol	RSC	Chernick, Skinner, et al., 1956	Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

References

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Chernick, Skinner, et al., 1956
Chernick, C.L.; Skinner, H.A.; Wadsö, I., Trans. Faraday Soc., 1956, 52, 1088. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Notes

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References

Symbols used in this document:

Δ_fH°_solid Enthalpy of formation of solid at standard conditions

Δ_rH° Enthalpy of reaction at standard conditions
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
Customer support for NIST Standard Reference Data products.

Δ_fH°_solid	Enthalpy of formation of solid at standard conditions
Δ_rH°	Enthalpy of reaction at standard conditions