vanadium tetrafluoride
- CAS Registry Number: 10049-16-8
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
+ vanadium tetrafluoride = (
• vanadium tetrafluoride)
By formula: F- + vanadium tetrafluoride = (F- • vanadium tetrafluoride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 87.2 ± 5.8 | kcal/mol | TDEq | Kuznetsov, Korobov, et al., 1989 | gas phase; Fluoride Affinity: 14.2±3.9 kcal/mol < UF4 |
| ΔrH° | 86.8 ± 6.5 | kcal/mol | TDEq | Sidorov, Boltalina, et al., 1989 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
Ion clustering data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
+ vanadium tetrafluoride = (
• vanadium tetrafluoride)
By formula: F- + vanadium tetrafluoride = (F- • vanadium tetrafluoride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 87.2 ± 5.8 | kcal/mol | TDEq | Kuznetsov, Korobov, et al., 1989 | gas phase; Fluoride Affinity: 14.2±3.9 kcal/mol < UF4 |
| ΔrH° | 86.8 ± 6.5 | kcal/mol | TDEq | Sidorov, Boltalina, et al., 1989 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kuznetsov, Korobov, et al., 1989
Kuznetsov, S.V.; Korobov, M.V.; Sidorov, L.N.,
Gas-Phase Negative Ion Chemistry of Platinum Metal Fluorides. III. Negative Ions of Pentafluorides.,
Int. J. Mass Spectrom. Ion Proc., 1989, 91, 3, 283, https://doi.org/10.1016/0168-1176(89)80083-7
. [all data]
Sidorov, Boltalina, et al., 1989
Sidorov, L.N.; Boltalina, O.V.; Borschevskii, A.Ya.,
Electron Affinities of Vanadium Fluorides. Additional Experimental Data and Corrections.,
Int. J. Mass Spectrom. Ion Proc., 1989, 87, 2, R1, https://doi.org/10.1016/0168-1176(89)80025-4
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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