Ethylbenzene
- Formula: C8H10
- Molecular weight: 106.1650
- IUPAC Standard InChIKey: YNQLUTRBYVCPMQ-UHFFFAOYSA-N
- CAS Registry Number: 100-41-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Benzene, ethyl-; Ethylbenzol; EB; Phenylethane; Aethylbenzol; Ethylbenzeen; Etilbenzene; Etylobenzen; NCI-C56393; UN 1175; α-Methyltoluene; NSC 406903
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 7.12 ± 0.20 | kcal/mol | Ccb | Prosen, Gilmont, et al., 1945 | Hf by Prosen, Johnson, et al., 1946; ALS |
ΔfH°gas | 11.7 ± 0.96 | kcal/mol | Ccb | N/A | Value computed using ΔfHliquid° from missing citation and ΔvapH° value of 10.1 kcal/mol from missing citation. recalculated with modern CO2,H2O thermo; estimated uncertainty (NOTE all values in source also have wrong sign); DRB |
ΔfH°gas | 16.6 | kcal/mol | N/A | Moureu and Andre, 1914 | Value computed using ΔfHliquid° value of 27.0 kj/mol from Moureu and Andre, 1914 and ΔvapH° value of 42.3 kj/mol from Prosen, Gilmont, et al., 1945.; DRB |
Quantity | Value | Units | Method | Reference | Comment |
S°gas | 86.2 ± 0.1 | cal/mol*K | N/A | Miller A., 1978 | S(298.16 K)=361.5 J/mol*K was obtained from earlier experimental data [ Guttman L., 1943].; GT |
Constant pressure heat capacity of gas
Cp,gas (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
10.60 | 50. | Thermodynamics Research Center, 1997 | Recommended values are in good agreement with other statistically calculated data [ Miller A., 1978, Taylor W.J., 1946].; GT |
13.80 | 100. | ||
17.29 | 150. | ||
21.16 | 200. | ||
27.935 | 273.15 | ||
30.449 | 298.15 | ||
30.638 | 300. | ||
40.619 | 400. | ||
49.374 | 500. | ||
56.585 | 600. | ||
62.502 | 700. | ||
67.419 | 800. | ||
71.551 | 900. | ||
75.057 | 1000. | ||
78.050 | 1100. | ||
80.609 | 1200. | ||
82.811 | 1300. | ||
84.706 | 1400. | ||
86.346 | 1500. |
Constant pressure heat capacity of gas
Cp,gas (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
38.06 ± 0.19 | 373.15 | Hossenlopp I.A., 1981 | Heat capacities determined from acoustical measurements [ Colgate S.O., 1990] (124.98, 138.21, 158.84, and 173.88 J/mol*K at 298.15, 323.15, 373.15, and 408.15 K, respectively) are slightly lower than calorimetric ones. Please also see Scott R.B., 1945.; GT |
39.257 ± 0.079 | 385.65 | ||
40.452 ± 0.081 | 398.15 | ||
42.772 ± 0.086 | 423.15 | ||
45.000 ± 0.091 | 448.15 | ||
47.168 ± 0.093 | 473.15 | ||
49.221 ± 0.098 | 498.15 | ||
51.15 ± 0.10 | 523.15 |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -2.98 ± 0.20 | kcal/mol | Ccb | Prosen, Gilmont, et al., 1945 | Hf by Prosen, Johnson, et al., 1946; ALS |
ΔfH°liquid | 1.6 ± 0.96 | kcal/mol | Ccb | N/A | recalculated with modern CO2,H2O thermo; estimated uncertainty (NOTE all values in source also have wrong sign); DRB |
ΔfH°liquid | 6.5 | kcal/mol | Ccb | Moureu and Andre, 1914 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -1092. ± 4. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 60.949 | cal/mol*K | N/A | Guthrie, Spitzer, et al., 1944 | DH |
S°liquid | 61.21 | cal/mol*K | N/A | Huffman, Parks, et al., 1930 | Extrapolation below 90 K, 61.09 J/mol*K.; DH |
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
44.17 | 293.31 | Andolenko and Grigor'ev, 1979 | T = 293 to 393 K. Unsmoothed experimental datum given as 1.741 kJ/kg*K.; DH |
44.3528 | 298.15 | Fortier and Benson, 1979 | DH |
44.3497 | 298.15 | Fortier and Benson, 1977 | DH |
44.402 | 298.15 | Fortier, Benson, et al., 1976 | DH |
38.5 | 295. | Tschamler, 1948 | DH |
44.41 | 298. | Kurbatov, 1947 | T = 15 to 18 C, mean Cp, four temperatures.; DH |
44.465 | 298.15 | Scott and Brickwedde, 1945 | T = 15 to 300 K.; DH |
44.410 | 298.15 | Guthrie, Spitzer, et al., 1944 | T = 13 to 305 K.; DH |
42.71 | 302.8 | de Kolossowsky and Udowenko, 1934 | DH |
42.71 | 302.7 | Kolosovskii and Udovenko, 1934 | DH |
44.60 | 298.15 | Blacet, Leighton, et al., 1931 | T = 286 to 368 K. Heat capacity reported as 0.420 cal g-1 K-1 at 25 C.; DH |
43.91 | 298.5 | Smith and Andrews, 1931 | T = 102 to 299 K. Value is unsmoothed experimental datum.; DH |
43.40 | 297.4 | Huffman, Parks, et al., 1930 | T = 93 to 305 K. Value is unsmoothed experimental datum.; DH |
43.40 | 303. | Willams and Daniels, 1924 | T = 303 to 343 K. Equation only.; DH |
44.10 | 298. | von Reis, 1881 | T = 292 to 425 K.; DH |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 409.3 ± 0.4 | K | AVG | N/A | Average of 79 out of 96 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 179. ± 2. | K | AVG | N/A | Average of 15 out of 16 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 178.15 | K | N/A | Scott and Brickwedde, 1945, 2 | Uncertainty assigned by TRC = 0.02 K; TRC |
Ttriple | 178. | K | N/A | Huffman, Parks, et al., 1930, 2 | Uncertainty assigned by TRC = 0.3 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 617. ± 2. | K | AVG | N/A | Average of 10 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 35.9 ± 0.9 | atm | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.374 | l/mol | N/A | Tsonopoulos and Ambrose, 1995 | |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 2.68 ± 0.010 | mol/l | N/A | Tsonopoulos and Ambrose, 1995 | |
ρc | 2.670 | mol/l | N/A | Simon, 1957 | Uncertainty assigned by TRC = 0.04 mol/l; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 10. ± 1. | kcal/mol | AVG | N/A | Average of 7 values; Individual data points |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
8.501 | 409.3 | N/A | Majer and Svoboda, 1985 | |
10.155 | 294.01 | N/A | Scott and Brickwedde, 1945 | DH |
9.99 | 313. | A | Stephenson and Malanowski, 1987 | Based on data from 298. to 420. K.; AC |
8.84 | 424. | A | Stephenson and Malanowski, 1987 | Based on data from 409. to 459. K.; AC |
8.56 | 472. | A | Stephenson and Malanowski, 1987 | Based on data from 457. to 554. K.; AC |
8.48 | 564. | A | Stephenson and Malanowski, 1987 | Based on data from 549. to 617. K.; AC |
9.70 | 335. | N/A | Paul, Krug, et al., 1986 | Based on data from 320. to 400. K.; AC |
9.68 ± 0.02 | 328. | C | Svoboda, Charvátová, et al., 1982 | AC |
9.44 ± 0.02 | 343. | C | Svoboda, Charvátová, et al., 1982 | AC |
9.23 ± 0.02 | 358. | C | Svoboda, Charvátová, et al., 1982 | AC |
9.56 | 345. | MM | Willingham, Taylor, et al., 1945 | Based on data from 330. to 410. K. See also Forziati, Norris, et al., 1949.; AC |
Enthalpy of vaporization
ΔvapH =
A exp(-βTr) (1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kcal/mol)
Tr = reduced temperature (T / Tc)
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Temperature (K) | A (kcal/mol) | β | Tc (K) | Reference | Comment |
---|---|---|---|---|---|
295. to 437. | 13.94 | 0.2823 | 617.1 | Majer and Svoboda, 1985 |
Entropy of vaporization
ΔvapS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
34.54 | 294.01 | Scott and Brickwedde, 1945 | DH |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
420.00 to 600.00 | 4.39965 | 1695.026 | -23.698 | Ambrose, Broderick, et al., 1967 | Coefficents calculated by NIST from author's data. |
329.74 to 410.27 | 4.06917 | 1419.315 | -60.539 | Williamham, Taylor, et al., 1945 |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
2.1945 | 178.15 | Scott and Brickwedde, 1945 | DH |
2.190 | 178.17 | Guthrie, Spitzer, et al., 1944 | DH |
2.19 | 178.2 | Domalski and Hearing, 1996 | AC |
2.190 | 178.0 | Huffman, Parks, et al., 1930 | DH |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
12.32 | 178.15 | Scott and Brickwedde, 1945 | DH |
12.29 | 178.17 | Guthrie, Spitzer, et al., 1944 | DH |
12.30 | 178.0 | Huffman, Parks, et al., 1930 | DH |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C8H9- + =
By formula: C8H9- + H+ = C8H10
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 406.0 ± 4.6 | kcal/mol | CIDT | Graul and Squires, 1990 | gas phase; From decarboxylation threshold. Stable form probably the spiro[2.5]octadienide Maas and van Keelen, 1989; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 397.7 ± 4.7 | kcal/mol | H-TS | Graul and Squires, 1990 | gas phase; From decarboxylation threshold. Stable form probably the spiro[2.5]octadienide Maas and van Keelen, 1989; B |
C8H9- + =
By formula: C8H9- + H+ = C8H10
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 379.7 ± 2.1 | kcal/mol | G+TS | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 373.3 ± 2.0 | kcal/mol | IMRE | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
By formula: 2H2 + C8H6 = C8H10
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -66.12 ± 0.06 | kcal/mol | Chyd | Davis, Allinger, et al., 1985 | liquid phase; solvent: Hexane; ALS |
ΔrH° | -64.7 ± 0.9 | kcal/mol | Chyd | Rogers and McLafferty, 1971 | liquid phase; solvent: Hydrocarbon; ALS |
ΔrH° | -70.7 ± 1.0 | kcal/mol | Chyd | Flitcroft and Skinner, 1958 | liquid phase; ALS |
By formula: NO- + C8H10 = (NO- • C8H10)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.5 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: C8H10 + 3H2 = C8H16
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -48.18 ± 0.10 | kcal/mol | Chyd | Dolliver, Gresham, et al., 1937 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -48.9 ± 0.1 kcal/mol; At 355 °K; ALS |
By formula: Cl- + C8H10 = (Cl- • C8H10)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 5.00 | kcal/mol | TDEq | French, Ikuta, et al., 1982 | gas phase; B |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
5.0 | 300. | PHPMS | French, Ikuta, et al., 1982 | gas phase; M |
+
= C8H9Br +
By formula: C8H10 + C6H5Br = C8H9Br + C6H6
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -0.14 ± 0.0050 | kcal/mol | Cm | Merdzhanov, Alenin, et al., 1982 | gas phase; Heat of isomerization at 349 K; ALS |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -28.01 ± 0.41 | kcal/mol | Chyd | Abboud, Jimenez, et al., 1995 | liquid phase; solvent: Hydrocarbon; Like gas phase; ALS |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 29.840 | kcal/mol | Eqk | Ghosh, Ram Das Guha, et al., 1945 | gas phase; ALS |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Prosen, Gilmont, et al., 1945
Prosen, E.J.; Gilmont, R.; Rossini, F.D.,
Heats of combustion of benzene, toluene, ethyl-benzene, o-xylene, m-xylene, p-xylene, n-propylbenzene, and styrene,
J. Res. NBS, 1945, 34, 65-70. [all data]
Prosen, Johnson, et al., 1946
Prosen, E.J.; Johnson, W.H.; Rossini, F.D.,
Heats of combustion and formation at 25°C of the alkylbenzenes through C10H14, and of the higher normal monoalkylbenzenes,
J. Res. NBS, 1946, 36, 455-461. [all data]
Moureu and Andre, 1914
Moureu, C.; Andre, E.,
Thermochimie des composes acetyleniques,
Ann. Chim. Phys., 1914, 1, 113-145. [all data]
Miller A., 1978
Miller A.,
Chemical thermodynamic properties of ethylbenzene,
J. Chem. Phys., 1978, 68, 1317-1319. [all data]
Guttman L., 1943
Guttman L., Jr.,
The thermodynamics of styrene (phenylethylene), including equilibrium of formation from ethylbenzene,
J. Am. Chem. Soc., 1943, 65, 1246-1247. [all data]
Thermodynamics Research Center, 1997
Thermodynamics Research Center,
Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]
Taylor W.J., 1946
Taylor W.J.,
Heats, equilibrium constants, and free energies of formation of the alkylbenzenes,
J. Res. Nat. Bur. Stand., 1946, 37, 95-122. [all data]
Hossenlopp I.A., 1981
Hossenlopp I.A.,
Vapor heat capacities and enthalpies of vaporization of four aromatic and/or cycloalkane hydrocarbons,
J. Chem. Thermodyn., 1981, 13, 423-428. [all data]
Colgate S.O., 1990
Colgate S.O.,
Acoustical determination of ideal gas heat capacities of three C-8 compounds,
Fluid Phase Equilib., 1990, 60, 191-203. [all data]
Scott R.B., 1945
Scott R.B.,
Specific heats of gaseous 1,3-butadiene, isobutene, styrene, and ethylbenzene,
J. Res. Nat. Bur. Stand., 1945, 34, 243-254. [all data]
Guthrie, Spitzer, et al., 1944
Guthrie, G.B., Jr.; Spitzer, R.W.; Huffman, H.M.,
Thermal data. XVIII. The heat capacity, heat of fusion, entropy and free energy of ethylbenzene,
J. Am. Chem. Soc., 1944, 66, 2120-2121. [all data]
Huffman, Parks, et al., 1930
Huffman, H.M.; Parks, G.S.; Daniels, A.C.,
Thermal data on organic compounds. VII. The heat capacities, entropies and free energies of twelve aromatic hydrocarbons,
J. Am. Chem. Soc., 1930, 52, 1547-1558. [all data]
Andolenko and Grigor'ev, 1979
Andolenko, R.A.; Grigor'ev, B.A.,
Investigation of isobaric heat capacity of aromatic hydrocarbons at atmospheric pressure, Iaz. Vyssh. Ucheb. Zaved.,
Neft i Gaz (11), 1979, 78, 90. [all data]
Fortier and Benson, 1979
Fortier, J.-L.; Benson, G.C.,
Heat capacities of some binary aromatic hydrocarbon mixtures containing benzene or toluene,
J. Chem. Eng. Data, 1979, 24(1), 34-37. [all data]
Fortier and Benson, 1977
Fortier, J.-L.; Benson, G.C.,
Excess heat capacities of binary mixtures of tetrachloromethane witlh some aromatic liquids at 298.15 K,
J. Chem. Thermodynam., 1977, 9, 1181-1188. [all data]
Fortier, Benson, et al., 1976
Fortier, J.-L.; Benson, G.C.; Picker, P.,
Heat capacities of some organic liquids determined with the Picker flow calorimeter,
J. Chem. Thermodynam., 1976, 8, 289-299. [all data]
Tschamler, 1948
Tschamler, H.,
Uber binare flussige Mischungen I. Mischungswarment, Volumseffekte und Zustandsdiagramme von chlorex mit benzol und n-alkylbenzolen,
Monatsh. Chem., 1948, 79, 162-177. [all data]
Kurbatov, 1947
Kurbatov, V.Ya.,
Specific heat of liquids. I. Specific heat of benzenoid hydrocarbons,
Zhur. Obshch. Khim., 1947, 17, 1999-2003. [all data]
Scott and Brickwedde, 1945
Scott, R.B.; Brickwedde, F.G.,
Thermodynamic properties of solid and liquid ethylbenzene from 0 to 300K,
J. Res., 1945, NBS 35, 501-512. [all data]
de Kolossowsky and Udowenko, 1934
de Kolossowsky, N.; Udowenko, W.W.,
Determination des chaleurs specifiques des liquides,
Compt. rend., 1934, 198, 1394-1395. [all data]
Kolosovskii and Udovenko, 1934
Kolosovskii, N.A.; Udovenko, W.W.,
Specific heat of liquids. II.,
Zhur. Obshchei Khim., 1934, 4, 1027-1033. [all data]
Blacet, Leighton, et al., 1931
Blacet, F.E.; Leighton, P.A.; Bartlett, E.P.,
The specific heats of five pure organic liquids and of ethyl alcohol-water mixtures,
J. Phys. Chem., 1931, 35, 1935-1943. [all data]
Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H.,
Thermal energy studies. I. Phenyl derivatives of methane,
ethane and some related compounds. J. Am. Chem. Soc., 1931, 53, 3644-3660. [all data]
Willams and Daniels, 1924
Willams, J.W.; Daniels, F.,
The specific heats of certain organic liquids at elevated temperatures,
J. Am. Chem. Soc., 1924, 46, 903-917. [all data]
von Reis, 1881
von Reis, M.A.,
Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht,
Ann. Physik [3], 1881, 13, 447-464. [all data]
Scott and Brickwedde, 1945, 2
Scott, R.B.; Brickwedde, F.G.,
Thermodynamic Properties of Solid and Liquid Ethylbenzene From 0 to 300 K,
J. Res. Natl. Bur. Stand. (U. S.), 1945, 35, 501-12. [all data]
Huffman, Parks, et al., 1930, 2
Huffman, H.M.; Parks, G.S.; Daniels, A.C.,
Thermal Data on Organic Compounds: VII The Heat Capacities, Entropies and Free Energies of Twelve Aromatic Hydrocarbons,
J. Am. Chem. Soc., 1930, 52, 1547-58. [all data]
Tsonopoulos and Ambrose, 1995
Tsonopoulos, C.; Ambrose, D.,
Vapor-Liquid Critical Properties of Elements and Compounds. 3. Aromatic Hydrocarbons,
J. Chem. Eng. Data, 1995, 40, 547-558. [all data]
Simon, 1957
Simon, M.,
Methods and Apparatus Used at the Bureau of Physicochemical Standards XV. Critical Constants and Straight-Line Diameters of Ten Hydrocarbons,
Bull. Soc. Chim. Belg., 1957, 66, 375-81. [all data]
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Paul, Krug, et al., 1986
Paul, Hanns-Ingolf; Krug, Joseph; Knapp, Helmut,
Measurements of VLE, hE and vE for binary mixtures of n-alkanes with n-alkylbenzenes,
Thermochimica Acta, 1986, 108, 9-27, https://doi.org/10.1016/0040-6031(86)85073-0
. [all data]
Svoboda, Charvátová, et al., 1982
Svoboda, Václav; Charvátová, Vladimíra; Majer, Vladimír; Hynek, Vladimír,
Determination of heats of vaporization and some other thermodynamic properties for four substituted hydrocarbons,
Collect. Czech. Chem. Commun., 1982, 47, 2, 543-549, https://doi.org/10.1135/cccc19820543
. [all data]
Willingham, Taylor, et al., 1945
Willingham, C.B.; Taylor, W.J.; Pignocco, J.M.; Rossini, F.D.,
Vapor pressures and boiling points of some paraffin, alkylcyclopentane, alkylcyclohexane, and alkylbenzene hydrocarbons,
J. RES. NATL. BUR. STAN., 1945, 35, 3, 219-17, https://doi.org/10.6028/jres.035.009
. [all data]
Forziati, Norris, et al., 1949
Forziati, Alphonse F.; Norris, William R.; Rossini, Frederick D.,
Vapor pressures and boiling points of sixty API-NBS hydrocarbons,
J. RES. NATL. BUR. STAN., 1949, 43, 6, 555-17, https://doi.org/10.6028/jres.043.050
. [all data]
Ambrose, Broderick, et al., 1967
Ambrose, D.; Broderick, B.E.; Townsend, R.,
The Vapour Pressures Above the Normal Boiling Point and the Critical Pressures of Some Aromatic Hydrocarbons,
J. Chem. Soc. A:, 1967, 633-641, https://doi.org/10.1039/j19670000633
. [all data]
Williamham, Taylor, et al., 1945
Williamham, C.B.; Taylor, W.J.; Pignocco, J.M.; Rossini, F.D.,
Vapor Pressures and Boiling Points of Some Paraffin, Alkylcyclopentane, Alkylcyclohexane, and Alkylbenzene Hydrocarbons,
J. Res. Natl. Bur. Stand. (U.S.), 1945, 35, 3, 219-244, https://doi.org/10.6028/jres.035.009
. [all data]
Domalski and Hearing, 1996
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Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
Cp,gas Constant pressure heat capacity of gas Cp,liquid Constant pressure heat capacity of liquid Pc Critical pressure S°gas Entropy of gas at standard conditions S°liquid Entropy of liquid at standard conditions T Temperature Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature Vc Critical volume ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ΔvapS Entropy of vaporization ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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