Hydrogen bromide

• Formula: BrH
• Molecular weight: 80.912
• IUPAC Standard InChI: InChI=1S/BrH/h1H Copy

  
• IUPAC Standard InChIKey: CPELXLSAUQHCOX-UHFFFAOYSA-N Copy
• CAS Registry Number: 10035-10-6
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Hydrobromic acid; Anhydrous hydrobromic acid; HBr; Hydrogen bromide, anhydrous-; Acide bromhydrique; Acido bromidrico; Bromowodor; Bromwasserstoff; Broomwaterstof; UN 1048; UN 1788; Hydrogen monobromide
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• Information on this page:
  • Constants of diatomic molecules
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 76
  • Henry's Law data
  • Gas phase ion energetics data
  • Ion clustering data
  • IR Spectrum
  • Mass spectrum (electron ionization)
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Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through December, 1976

Notes

References

Go To: Top, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Barrow and Stamper, 1961
Barrow, R.F.; Stamper, J.G., The absorption spectrum of gaseous hydrogen bromide in the Schumann region. I. Rotational analysis, Proc. R. Soc. London A, 1961, 263, 259. [all data]

Stamper, 1962
Stamper, J.G., The absorption spectrum of DBr in the vacuum ultraviolet region, Can. J. Phys., 1962, 40, 1279. [all data]

Ginter and Tilford, 1971
Ginter, M.L.; Tilford, S.G., Electronic spectra and structure of the hydrogen halides. States associated with the (σ²π³)cπ and (σ²π³) cσ configurations of HBr and DBr, J. Mol. Spectrosc., 1971, 37, 159. [all data]

Stamper and Barrow, 1961
Stamper, J.G.; Barrow, R.F., The V(¹Σ⁺)-N(¹Σ⁺) transition of hydrogen bromide, J. Phys. Chem., 1961, 65, 250. [all data]

Bates, Halford, et al., 1935
Bates, J.R.; Halford, J.O.; Anderson, L.C., A comparison of some physical properties of hydrogen and deuterium bromides, J. Chem. Phys., 1935, 3, 531. [all data]

Goodeve and Taylor, 1935
Goodeve, C.F.; Taylor, A.W.C., The continuous absorption spectrum of hydrogen bromide, Proc. R. Soc. London A, 1935, 152, 221. [all data]

Datta and Chakravarty, 1941
Datta, S.; Chakravarty, B., The continuous absorption spectra of the hydrogen-halides. Part I - HBr, Proc. Natl. Inst. Sci. India, 1941, 7, 297. [all data]

Romand, 1949
Romand, J., Absorption ultraviolette dans la region de Schumann etude de: ClH, BrH et lH gazeux, Ann. Phys. (Paris), 1949, 4, 527. [all data]

Huebert and Martin, 1968
Huebert, B.J.; Martin, R.M., Gas-phase far-ultraviolet absorption spectrum of hydrogen bromide and hydrogen iodide, J. Phys. Chem., 1968, 72, 3046. [all data]

Rank, Fink, et al., 1965
Rank, D.H.; Fink, U.; Wiggins, T.A., High resolution measurements on the infrared absorption spectrum of HBr, J. Mol. Spectrosc., 1965, 18, 170. [all data]

Hansler and Oetjen, 1953
Hansler, R.L.; Oetjen, R.A., The infrared spectra of HCl, DCl, HBr, and NH₃ in the region from 40 to 140 microns, J. Chem. Phys., 1953, 21, 1340. [all data]

Jones and Gordy, 1964
Jones, G.; Gordy, W., Submillimeter-wave spectra of HCl and HBr, Phys. Rev., 1964, 136, 1229. [all data]

Van Dijk and Dymanus, 1969
Van Dijk, F.A.; Dymanus, A., Hyperfine structure of the rotational spectrum of HBr and in the submillimeter wave region, Chem. Phys. Lett., 1969, 4, 170. [all data]

Cherlow, Hyatt, et al., 1975
Cherlow, J.M.; Hyatt, H.A.; Porto, S.P.S., Raman scattering in hydrogen halide gases, J. Chem. Phys., 1975, 63, 3996. [all data]

Dabbousi, Meerts, et al., 1973
Dabbousi, O.B.; Meerts, W.L.; de Leeuw, F.H.; Dymanus, A., Stark-Zeeman hyperfine structure of H⁷⁹Br and H⁸¹Br by molecular-beam electric-resonance spectroscopy, Chem. Phys., 1973, 2, 473. [all data]

Bunker, 1972
Bunker, P.R., On the breakdown of the Born-Oppenheimer approximation for a diatomic molecule, J. Mol. Spectrosc., 1972, 5, 478. [all data]

Chamberlain and Gebbie, 1965
Chamberlain, J.E.; Gebbie, H.A., Sub-millimetre dispersion and rotational line strengths of the hydrogen halides, Nature (London), 1965, 208, 480. [all data]

Atwood, Vu, et al., 1967
Atwood, M.R.; Vu, H.; Vodar, B., Forme et structures fines de la bande induite par la pression dans la bande fondamentale de vibration-rotation des molecules HF, HCl et HBr, Spectrochim. Acta, 1967, 23, 553. [all data]

Weiss and Cole, 1967
Weiss, S.; Cole, R.H., Pressure-induced rotational quadrupole spectra of HCl and HBr, J. Chem. Phys., 1967, 46, 644. [all data]

Babrov, 1964
Babrov, H.J., Strengths and self-broadened widths of the lines of the hydrogen bromide fundamental band, J. Chem. Phys., 1964, 40, 831. [all data]

Pourcin, Bachet, et al., 1967
Pourcin, J.; Bachet, G.; Coulon, R., Possibilite d'une absorption non resonnante induite dans le spectre de rotation pure de HBr gazeux perturbe par des gaz comprimes, C.R. Acad. Sci. Paris, Ser. B, 1967, 264, 975. [all data]

van Dijk and Dymanus, 1974
van Dijk, F.A.; Dymanus, A., Hyperfine and Stark spectrum of DBr in the millimeter-wave region, Chem. Phys., 1974, 6, 474. [all data]

Schurin and Rollefson, 1957
Schurin, B.; Rollefson, R., Infrared dispersion of hydrogen bromide, J. Chem. Phys., 1957, 26, 1089. [all data]

Tokuhiro, 1967
Tokuhiro, T., Vibrational and rotational effects on the nuclear quadrupole coupling constants in hydrogen, deuterium, and tritium halides, J. Chem. Phys., 1967, 47, 109. [all data]

van Dijk and Dymanus, 1970
van Dijk, F.A.; Dymanus, A., The electric dipole moment of HI and HBr, Chem. Phys. Lett., 1970, 5, 387. [all data]

Watanabe, 1957
Watanabe, K., Ionization potentials of some molecules, J. Chem. Phys., 1957, 26, 542. [all data]

Frost, McDowell, et al., 1967
Frost, D.C.; McDowell, C.A.; Vroom, D.A., Photoelectron spectra of the halogens and the hydrogen halides, J. Chem. Phys., 1967, 46, 4255. [all data]

Lempka, Passmore, et al., 1968
Lempka, H.J.; Passmore, T.R.; Price, W.C., The photoelectron spectra and ionized states of the halogen acids, Proc. Roy. Soc. (London), 1968, A304, 53. [all data]

Delwiche, Natalis, et al., 1972
Delwiche, J.; Natalis, P.; Momigny, J.; Collin, J.E., On the photoelectron spectra of HBr and DBr, J. Electron Spectrosc. Relat. Phenom., 1972, 1, 219. [all data]

Terwilliger and Smith, 1975
Terwilliger, D.T.; Smith, A.L., Autoionization in diatomics: measured line shape parameters and predicted photoelectron spectra for some autoionizing states of the hydrogen halides, J. Chem. Phys., 1975, 63, 1008. [all data]

Naude and Verleger, 1950
Naude, S.M.; Verleger, H., The vibration-rotation bands of the hydrogen halides HF, H³⁵Cl, H³⁷Cl, H⁷⁹Br, H⁸¹Br and H¹²⁷I, Proc. Phys. Soc. London Sect. A, 1950, 63, 470. [all data]

Thompson, Williams, et al., 1952
Thompson, H.W.; Williams, R.L.; Callomon, H.J., The fundamental vibration band of hydrogen bromide, Spectrochim. Acta, 1952, 5, 313. [all data]

Plyler, 1960
Plyler, E.K., Infrared spectrum of hydrobromic aid, J. Res. Nat. Bur. Stand. Sect. A, 1960, 64, 377. [all data]

Bernage, Niay, et al., 1973
Bernage, P.; Niay, P.; Bocquet, H.; Houdart, R., Etude des bandes d'absorption infrarouges v_0-3, v_0-4, v_0-5 de l'acide bromhydrique gazeux a l'aide d'un spectrometre sisam, Rev. Phys. Appl., 1973, 8, 333. [all data]

Mould, Price, et al., 1960
Mould, H.M.; Price, W.C.; Wilkinson, G.R., Infra-red emission from gases excited by a radio-frequency discharge, Spectrochim. Acta, 1960, 16, 479. [all data]

James and Thibault, 1965
James, T.C.; Thibault, R.J., Infrared-emission spectrum of HBr excited in an electric discharge. Determination of molecular constants, J. Chem. Phys., 1965, 42, 1450. [all data]

Ogilvie and Koo, 1976
Ogilvie, J.F.; Koo, D., Dunham potential energy coefficients of the hydrogen halides and carbon monoxide, J. Mol. Spectrosc., 1976, 61, 332-336. [all data]

Babrov, Shabott, et al., 1965
Babrov, H.J.; Shabott, A.L.; Rao, B.S., Matrix elements for vibration-rotation transitions in the HBr overtone and hot bands, J. Chem. Phys., 1965, 42, 4124. [all data]

Rao and Lindquist, 1968
Rao, B.S.; Lindquist, L.H., Dipole matrix elements for vibration-rotation lines in the 2-0 band of the hydrogen bromide molecule, Can. J. Phys., 1968, 46, 2739. [all data]

Gustafson and Rao, 1970
Gustafson, B.P.; Rao, B.S., Dipole matrix elements for vibration-rotation lines in the fundamental band of the hydrogen bromide molecule, Can. J. Phys., 1970, 48, 330. [all data]

Urquhart, Clark, et al., 1972
Urquhart, D.N.; Clark, T.D.; Rao, B.S., The dipole moment function of H⁷⁹Br molecule, Z. Naturforsch. A, 1972, 27, 1563. [all data]

Jacobi, 1967
Jacobi, N., Electrical anharmonicities of diatomic molecules, J. Mol. Spectrosc., 1967, 22, 76. [all data]

Tipping and Herman, 1970
Tipping, R.H.; Herman, R.M., Line intensities in HBr vibration-rotation spectra, J. Mol. Spectrosc., 1970, 36, 404. [all data]

Rao, 1971
Rao, B.S., Vibration-rotation band strengths and dipole moment function of the H⁷⁹Br molecule, J. Phys. B:, 1971, 4, 791. [all data]

Notes

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